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Received May 23, 2022
Revised July 23, 2022
Accepted July 29, 2022
- Acknowledgements
- The authors thank the Iranian National Science Foundation (grant INSF 99017447), Research Council of the University of Tehran, Shahid Chamran University of Ahvaz and Sharif University of Technology for financial support
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Organic/inorganic nanohybrid of MgAl@CuFe2O4-polylysine for hazardous Cr(VI) and methyl orange uptake: Multivariate optimization and isotherm study
1Department of Chemistry, Faculty of Science, Shahid Chamran University of Ahvaz, Ahvaz, Iran 2School of Chemistry, University College of Science, University of Tehran, Tehran, Iran 3Department of Chemistry, Sharif University of Technology, Tehran, Iran, P. O. Box 11155-3615
h.alijani@scu.ac.ir
Korean Journal of Chemical Engineering, April 2023, 40(4), 952-963(12), 10.1007/s11814-022-1244-7
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Abstract
An efficient organic/inorganic magnetic nanohybrid of MgAl@CuFe2O4-polylysine was successfully synthesized and employed as a suitable adsorbent for removal Cr(VI) and methyl orange from water solution. The prepared
nanohybrid was characterized by X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy, vibrating sample magnetometer and thermogravimetric analysis. The nanohybrid of MgAl@CuFe2O4-polylysine
was employed to adsorb anionic species, i.e., Cr(VI) and methyl orange through electrostatic attraction, ligand exchange
and ion exchange. Multivariate optimization with Box-Behnken design was used to evaluate effective parameters such
as dosage of adsorbent, solution pH and contact time on adsorption and their interaction. Results showed that pH,
contact time and adsorbent dosage are effective parameters for Cr(VI) adsorption; however, the pH of the solution is
the sole effective parameter for methyl orange adsorption. Both analyte adsorptions are fast with adsorption times less
than 15 min. Isotherm study revealed that the prepared nanohybrid is a highly efficient adsorbent for methyl orange
and Cr(VI) with adsorption capacity of 693.6 and 281.8 mg g1
, respectively. Isotherm study showed that adsorption of
both analytes well fitted with the Freundlich adsorption isotherm model, which indicated multilayer adsorption on the
heterogeneous surface. The magnetic saturation for the prepared adsorbent was 12.64 emu g1
, which was adequate and
suitable for magnetic separation of samples. The prepared adsorbent was regenerated using ethanol-aquaeous NaOH
solution as it shows 90% removal efficiency after three cycles
Keywords
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2. L. Hu, S. Tao, J. Xian, X. Zhang, Y. Liu, X. Zheng and X. Lin, Chin.J. Chem. Eng., 43, 230 (2022).
3. R. Kaveh and M. Bagherzadeh, Diam. Relat. Mater., 124, 108923(2022).
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8. Q. Wang, Y. Guan, X. Liu, M. Yang and X. Ren, Chin. J. Chem.Eng., 20, 105 (2012).
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37. H. Zaghouane-boudiaf, M. Boutahala and L. Arab, Chem. Eng. J.,187, 142 (2012).
38. B. J. Kim, S. G. Oh, M. G. Han and S. S. Im, Langmuir, 16, 5841(2000).
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41. M. J. Pirouz, M. Hossein Beyki and F. Shemirani, Food Chem.,170, 131 (2015).
42. X. Ge, C. D. Gu, X. L. Wang and J. P. Tu, J. Colloid Interface Sci., 45,134 (2015).
43. M. Huy, N. Hoa, T. Dung, T. T. S. Pham, V. K. Nguyen, T. T. T. Vu,T. Kim and P. Nguyen, Chemosphere, 85, 1269 (2011).
44. A. E. Chávez-guajardo, J. C. Medina-llamas, L. Maqueira, C. A. S.Andrade, K. G. B. Alves and C. P. Melo, Chem. Eng. J., 281, 826(2015).
45. P. P. Huang, C. Y. Cao, F. Wei, Y. B. Sun and W. G. Song, RSC Adv.,5, 10412 (2015).
46. K. Yang, L. G. Yan, Y. M. Yang, S. J. Yu, R. Shan, H. Yu, B. Zhu and B. Du, Sep. Purif. Technol., 124, 36 (2014).
47. J. Zhou, S. Yang, J. Yu and Z. Shu, J. Hazard. Mater., 192, 1114(2011).
48. M. Hossein Beyki, M. Mohammadirad, F. Shemirani and A. A.Saboury, Carbohydr. Polym., 157, 438 (2017).
49. J. P. Pouget, M. E. Jozefowicz, A. J. Epstein, X. Tang and A. G. MacDiarmid, Macromolecules, 24, 779 (1991).
50. J. Nonkumwong, P. Pakawanit, A. Wipatanawin, P. Jantaratana, S.Ananta and L. Srisombat, Mater. Sci. Eng. C., 61, 123 (2016).
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53. S. H. Hosseini and A. Asadnia, J. Nanomater., 2012, 1 (2012).
54. S. Jorfi, R. Darvishi Cheshmeh Soltani, M. Ahmadi, A. Khataee and M. Safari, Environ. Manag. Today, 187, 111 (2017).
55. A. M. Bandpei, S. M. Mohseni, A. Sheikhmohammadi, M. Sardar,M. Sarkhosh, M. Almasian, M. Avazpour, Z. Mosallanejad, Z.
Atafar, S. Nazari and S. Rezaei, Korean J. Chem. Eng., 32, 1 (2015).
56. L. G. Yan, Y. Y. Xu, H. Q. Yu, X. Xin, Q. Wei and B. Du, J. Hazard.Mater., 179, 244 (2010).
57. Y. Xue, H. Hou and S. Zhu, J. Hazard. Mater., 162, 973 (2009).
58. M. Hossein Beyki, F. Feizi and F. Shemirani, React. Funct. Polym.,103, 81 (2016).
59. Z. Dong, H. Xu, Z. Bai, H. Wang, L. Zhang, X. Luo, Z. Tang, R.Luquec and J. Xuan, RSC Adv., 5, 78352 (2015).
60. Q. Xin, J. Fu, Z. Chen, S. Liu, Y. Yan, J. Zhang and Q. Xu, J. Environ. Chem. Eng., 3, 1637 (2015).
61. R. Kaveh, H. Alijani, M. Hossein Beyki and M. Jafari Pirouz,Desalin Water Treat., 212, 376 (2021).
62. F. Q. An, R. Y. Wu, M. Li, T. P. Hu, J. F. Gao and Z. G. Yuan, React.Funct. Polym., 118, 42 (2017).
