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- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
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Received July 1, 2022
Revised September 11, 2022
Accepted October 17, 2022
- Acknowledgements
- We greatly appreciate the financial support from the projects of NSFC (No. 22106051) and Jilin Science and Technology Bureau (No. 20190104190, No.20190104189).
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Highly efficient, durable and eco-friendly intumescent flame retardant for wool fabrics
1Centre of Analysis and Measurement, Jilin Institute of Chemical Technology, Jilin 132022, China 2School of Materials Science and Engineering, Jilin Institute of Chemical Technology, Jilin 132022, China
2312329010@qq.com
Korean Journal of Chemical Engineering, April 2023, 40(4), 999-1013(15), 10.1007/s11814-022-1318-6
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Abstract
According to the requirements of flame retardant and environmental protection of wool fabrics, a phosphorus-nitrogen intumescent flame-retardant (IFR) system was constructed on the surface of wool fabrics based on
dip-rolling-drying process with DEA serving as carbonizing agent, phosphorous acid and phosphoric acid used as
acids, and urea serving as blowing agent. Ammonium N-ethoxy-n-methylene phosphonate-n-ethyl phosphate (ANPP)
was designed and the treated wool fabrics with a weight gain (WG) of 27.4% presented highly flame retardancy and
exhibited a high limiting oxygen index (LOI) of 37.8%; after 50 laundering cycles (LCs), LOI can still be remained at
30.5%. Self-extinguishing properties in the vertical combustion. The cone calorimeter (CONE) test verified that the
peak heat release rate (PHRR) of the untreated wool fabrics declined to 82.2 from 251.7 kW/m2
after ANPP treatment,
and the total heat release (THR) was reduced to 4.4 from 37.9 MJ/m2
. In addition, the physical properties were maintained in the usable range. The flame-retardant mechanism analysis showed that the dense phosphorus-nitrogen char
layer shaped effectively prevented the release of heat and spread of flammable volatile substances in the condensed
phase. This study supplies novel ideas on devising and manufacturing of environmentally friendly treated wool fabrics
with superior flame retardancy, durability, and high efficiency
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50. L. Chen and Y. Z. Wang, Polym. Adv. Technol., 21, 1 (2010).
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55. J. Gorham, J. Torres, G. Wolfe, A. d’Agostino and D. H. Fairbrother,J. Phys. Chem. B, 109, 20379 (2005)
