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- In relation to this article, we declare that there is no conflict of interest.
- Publication history
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Received October 27, 2022
Revised December 21, 2022
Accepted January 31, 2023
- Acknowledgements
- This research was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Science and ICT (NRF-2019R1A2C2088174), the Korea Institute of Energy Technology Evaluation and Planning (KETEP) and the Ministry of Trade, Industry & Energy (MOTIE) of the Republic of Korea (20212010100040) and the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIT) (NRF2021R1A5A1084921).
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Enhanced catalytic complete oxidation of 1,2-dichloroethane to CO2 over the Al-based oxide supported CuClx composite catalysts
Department of Chemical Engineering, Pohang University of Science and Technology (POSTECH), 77 Cheongam-ro, Nam-gu, Pohang, Gyeongbuk 37673, Korea
kimwb@postech.ac.kr
Korean Journal of Chemical Engineering, May 2023, 40(5), 1055-1062(8), 10.1007/s11814-023-1435-x
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Abstract
Chlorinated volatile organic compounds (CVOCs) have been regarded as hazardous atmospheric pollutants, and catalytic oxidative destruction has been considered as the most efficient method to handle such contaminants. Herein, characteristics of Al, Si and Ti based supporting materials were modified with cupric chloride to
enhance catalytic performance for the complete oxidation of 1,2-dichlroethane (DCE). According to the supporting
materials in the presence or absence of active materials, physicochemical properties of catalysts appear to be quite differentiated, and the relationship between modified properties and its catalytic performance was observed and discussed. Among the studied catalysts, CuCl2/Al1Ti1Ox composite showed the highest catalytic performance, which could
be attributed to several beneficial effects associated with proper textural property, abundant acid sites and oxidizing
ability. This catalyst designing strategy described in this study suggests a prospective way to develop efficient catalysts
fashioned of non-precious, earth-abundant materials for the catalytic oxidation of CVOCs
Keywords
References
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47. M. C. Biesinger, Surf. Interface Anal., 49, 1325 (2017).
48. A. Sápi, U. Kashaboina, K. B. Ábrahámné, J. F. Gómez-Pérez, I.Szenti, G. Halasi, K. János, N. Balázs, V. Tamásm, K. Ákosm and Z. Kónya, Front. Mater., 6, 127 (2019)
