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- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
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Received August 7, 2022
Revised November 25, 2022
Accepted December 11, 2022
- Acknowledgements
- We acknowledge financial support from National Natural Science Foundation of China (Nos. 51907173, 21504033, 21673201), Top-notch Academic Programs Project of Jiangsu Higher Education Institutions, China (TAPP). We also acknowledge the Priority Academic Program Development of Jiangsu Higher Education Institutions, China.
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Controllable synthesis of bowl-shaped porous carbon materials through didodecyldimethylammonium bromide for high performance supercapacitors
1College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu 225002, P. R. China 2School of Chemistry and Environmental Engineering, Yancheng Teachers University, Yancheng 224007, P. R. China
shenming@yzu.edu.cn, xuguodong003@gmail.com
Korean Journal of Chemical Engineering, June 2023, 40(6), 1331-1339(9), 10.1007/s11814-022-1375-x
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Abstract
AbstractA series of bowl-shaped porous carbon materials was successfully synthesized by the use of didodecyldimethylammonium bromide as the soft template agent. By controlling the dosage of the soft template agent and the water/
ethanol ratio of the solvent, the size and structure of the carbon materials can be precisely controlled. The prepared carbon materials with stacked bowl structure have good specific surface area (1,380.20 m2
g1
), large pore volume
(1.27 cm3
g1
) and high heteroatom N doping amount (6.68 at.%). Moreover, electrochemical tests in 6 M KOH demonstrated impressive electrochemical performance, where the specific capacity of the typical materials was measured
to be 191.0 F g1
(at the current density of 1 A g1
), and the capacity retention rate of typical materials was 80% (at the
current density of 10 A g1
).
Keywords
References
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5. X. Y. Chen, C. Chen, Z. J. Zhang and D. H. Xie, J. Mater. Chem. A,1, 7379 (2013).
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