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- In relation to this article, we declare that there is no conflict of interest.
- Publication history
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Received October 4, 2022
Revised December 7, 2022
Accepted December 26, 2022
- Acknowledgements
- This research was supported by Korea Institute of Planning and Evaluation for Technology in Food, Agriculture and Forestry (IPET) and Korea Smart Farm R&D Foundation (KosFarm) through Smart Farm Innovation Technology Development Program, funded by Ministry of Agriculture, Food and Rural Affairs (MAFRA) and Ministry of Science and ICT (MSIT), Rural Development Administration (RDA) (421042-04). This work was also supported the Industrial Strategic Technology Development Program (20012763) funded by the Minist
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Preparation of carbonaceous monolith from polyacrylonitrile@lignin hybrid composite and its sensing and adsorption capability
Byung-Ho Kang1†
Jinyong Hong2†
Oh-Nyoung Hu1
Minji Kang3
Jiyun Moon3
Jooyoung Seo3
Gyeongrim Han3
Suhyun Shin3
Chang-Soo Lee4 5†
Sung-Hoon Park1†
Joonwon Bae3†
1Department of Mechanical Engineering, Soongsil University, Seoul 06978, Korea 2Center for C1 Gas & Carbon Convergent Research, Korea Research Institute of Chemical Technology (KRICT), Yuseong-gu, Daejeon 34114, Korea 3Department of Applied Chemistry, Dongduk Women’s University, Seoul 02748, Korea 4Bionanotechnology Research Center, Korea Research Institute of Bioscience & Biotechnology (KRIBB), Yuseong-gu, Daejeon 34141, Korea 5Department of Biotechnology, University of Science & Technology (UST), Yuseong-gu, Daejeon 34113, Korea
leopark@ssu.ac.kr, redsox7@dongduk.ac.kr, cslee@kribb.re.kr, joonwonbae@gmail.com
Korean Journal of Chemical Engineering, June 2023, 40(6), 1510-1517(8), 10.1007/s11814-023-1389-z
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Abstract
A carbonaceous monolith material was produced from polyacrylonitrile@lignin (PAN@lig) composite
hybrid; the sensing and adsorption capabilities of the material were evaluated. Because the two carbon-based precursors, PAN and lignin, have different characteristics, the resulting carbonaceous hybrid material was expected to exhibit
unique properties. The controlled carbonization of PAN@lig produced a carbonaceous monolith with characteristic
external and internal structures. Electron microscopy and cyclic voltammetry analyses of the morphological and electrochemical features of the monolith revealed stable structural and electrochemical properties. The hybrid, which acted
as an electrochemical capacitor because of the electrical conductivity of the monolith, was suitable for use as a sensing
material. The feasibility of using the carbonaceous monolith as a sensing medium was demonstrated by extensive electrical measurements of a simple sensor geometry. The carbonaceous hybrid also demonstrated the capacity to adsorb
toxic chemicals/substances, such as radioactive heavy metal ions. The adsorption behavior was analyzed using several
isotherm and kinetic models.
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