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- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
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Received November 6, 2022
Revised January 26, 2023
Accepted January 31, 2023
- Acknowledgements
- Princess Nourah bint Abdulrahman University, located in Riyadh, Saudi Arabia, is supporting researchers under Project Number (PNURSP2023R55). The authors extend their appreciation to the Research Center for Advanced Materials Science (RCAMS), King Khalid University, Saudi Arabia, for funding this work under grant number KKU/RCAMS/023/23.
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Partial sulfur doping induced variation in morphology of MnFe2O4 with enhanced electrochemical performance for energy storage devices
Muhammad Abdullah1
Fatemah Farraj Alharbi2
Rabia Yasmin Khosa3
Huda A Alburaih2
Sumaira Manzoor1
Abdul Ghafoor Abid4
Haitham Elhosiny Al5 6
Mhammad Suleman Waheed7
Muhammad Numair Ansari4
Hafiz Muhammad Tahir Farid8†
1Department of Chemistry, Government College University, Lahore 2Department of Physics, College of Science, Princess Nourah bint Abdulrahman University, P.O. Box 84428, Riyadh 11671, Saudi Arabia 3University of Education, Lahore, Dera Ghazi Khan Campus, D. G. Khan 32200, Pakistan 4Institute of Chemical Sciences, Bahauddin Zakariya University, Multan 5Research Center for Advanced Materials Science (RCAMS), King Khalid University, Abha 61413, P.O. Box 9004, Saudi Arabia 6Physics Department, Faculty of Science, Zagazig University, Zagazig, Egypt 7Centre of Excellence in Solid State Physics, University of the Punjab, Lahore 54590, Pakistan 8Department of Physics, Government College Taunsa Sharif- 32200, Pakistan
tahirfaridbzu@gmail.com
Korean Journal of Chemical Engineering, June 2023, 40(6), 1518-1528(11), 10.1007/s11814-023-1423-1
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Abstract
Manganese ferrite offers several advantages when employed as an electrocatalytic material for supercapacitors, including outstanding cycle stability and energy capacity. When compared to identical-metal sulfides, specific
capacitance (Csp) of MnFe2O4 remains inadequate. So, using the hydrothermal synthesis technique, partial sulfur doping
of MnFe2O4 was achieved to investigate the synergetic effect of oxides and sulfides. Various spectroscopic and microscopic studies demonstrate that adding sulfur atoms into MnFe2O4 increases the lattice parameters, which improves
electrochemical performance. At a current density around 2 A g1
, then calculating MnFe2O4 with partial sulfur doping has a Csp of 1,201.60 F g1
, that is greater than 784.0 F g1
of pure MnFe2O4. Maximum energy density (Ed) of
93.62 Wh kg1
was produced with a power density (Pd) of 749 W kg1
. The current study depicts that partial sulfur
doping can enhance the electrochemical behavior of MnFe2O4. As a result, the present work shows more effective in
field of energy storage by enhancing their poor electrochemical performance.
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2. S. Manzoor, A. G. Abid, S. Aman, M. Abdullah, A. R. Rashid, H. M.Ali, T. E. Ali, M. A. Assiri, M. N. Ashiq and T. A. Taha, Ceram. Int.,48, 36975 (2022).
3. S. Gouadria, M. Abudllah, Z. Ahmad, P. John, M. U. Nisa, S. Manzoor, S. Aman, M. N. Ashiq and M. I. Ghori , Ceram. Int., 49, 4281(2022).
4. X. Li, Y. Li, X. Zhao, F. Kang and L. Dong, Energy Storage Mater.,53, 505 (2022).
5. T. Kosukoglu, M. Carpan, S. Riza Tokgoz and A. Peksoz, Mater.Sci. Eng. B., 286, 116032 (2022).
6. B. T. Al-Abawi, N. Parveen and S. A. Ansari, Sci. Rep., 12, 1 (2022).
7. W. K. Chee, H. N. Lim, I. Harrison, K. F. Chong, Z. Zainal, C. H.Ng and N. M. Huang, Electrochim. Acta, 157, 88 (2015).
8. J. Liang, Y. Feng, L. Liu, S. Li, C. Jiang and W. Wu, J. Mater. Chem.A, 7, 15960 (2019).
9. G. Qiu, Q. Qiu, L. Qing, J. Zhou, X. Xu and S. Zhao, J. Phys. Chem.C., 19, 8218 (2022).
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11. S. A. Beknalkar, A. M. Teli, T. S. Bhat, K. K. Pawar, S. S. Patil, N. S.Harale, J. C. Shin and P. S. Patil, J. Mater. Sci. Technol., 130, 227(2022).
12. T. Schoetz, L. W. Gordon, S. Ivanov, A. Bund, D. Mandler and R. J.Messinger, Electrochim. Acta, 412, 140072 (2022).
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15. R. Yan, M. Antonietti and M. Oschatz, Adv. Energy Mater., 8,1800026 (2018).
16. M. Kim and J. Kim, Phys. Chem. Chem. Phys., 16, 11323 (2014).
17. B.E. Conway and W.G. Pell, J. Solid State Electrochem., 7, 637 (2003).
18. J. Yan, Z. Fan, W. Sun, G. Ning, T. Wei, Q. Zhang, R. Zhang, L. Zhi and F. Wei, Adv. Funct. Mater., 22, 2632 (2012).
19. H. Ren, L. Zhang, J. Zhang, T. Miao, R. Yuan, W. Chen, Z. Wang,J. Yang and B. Zhao, Carbon N Y., 198, 46 (2022).
20. M. Abdullah, P. John, Z. Ahmad, M. N. Ashiq, S. Manzoor, M. I.Ghori, M. U. Nisa, A. G. Abid, K. Y. Butt and S. Ahmed, Appl.Nanosci., 11, 2361 (2021).
21. M. U. Nisa, S. Manzoor, A. G. Abid, N. Tamam, M. Abdullah, M.Najam-Ul-Haq, M. S. Al-Buriahi, Z. A. Alrowaili, Z. M. M. Mahmoud and M. N. Ashiq, Fuel, 321, 124086 (2022).
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25. B. wen Deng, Y. Yang, B. Yin and M. bo Yang, J. Colloid Interface Sci., 594, 770 (2021).
26. D. Zheng, C. Sun, W. Pan, G. Guo, Y. Zheng, C. Liu and J. Zhu, Energy Fuels, 35, 16915 (2021).
27. X. Li, X. Li, G. Wang, X. Wang and J. Ji, J. Mater. Chem. A, 1, 10103(2013).
28. D. P. Mali, R. T. Patil, A. S. Patil and V. J. Fulari, Chem. Phys. Lett.,770, 138431 (2021).
29. D. Zhou, H. Lin, F. Zhang, H. Niu, L. Cui, Q. Wang and F. Qu,Electrochim. Acta, 161, 427 (2015).
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31. Y. C. Chen, Y. K. Hsu, Y. G. Lin, Y. K. Lin, Y. Y. Horng, L. C. Chen and K. H. Chen, Electrochim. Acta, 56, 7124 (2011).
32. C. Justin Raj, R. Manikandan, P. Sivakumar, D. O. Opar, A. Dennyson Savariraj, W. J. Cho, H. Jung and B. C. Kim, J. Alloys Compd.,
892, 162199 (2022).
33. X. Gao, W. Wang, J. Bi, Y. Chen, X. Hao, X. Sun and J. Zhang, Electrochim. Acta, 296, 181 (2019).
34. S. S. Raut and B. R. Sankapal, Electrochim. Acta, 198, 203 (2016).
35. S. Maitra, R. Mitra and T. K. Nath, Curr. Appl. Phys., 27, 73 (2021).
36. M. Fei, R. Zhang, L. Li, J. Li, Z. Ma, K. Zhang, Z. Li, Z. Yu, Q. Xiao and D. Yan, Electrochim. Acta, 368, 137586 (2021).
37. D. P. Sherstyuk, A. Y. Starikov, V. E. Zhivulin, D. A. Zherebtsov,S. A. Gudkova, N. S. Perov, Y. A. Alekhina, K. A. Astapovich, D. A.
Vinnik and A. V. Trukhanov, Ceram. Int., 47, 12163 (2021).
38. M. Hassan, Y. Slimani, M. A. Gondal, M. J. S. Mohamed, S. Güner,M. A. Almessiere, A. M. Surrati, A. Baykal, S. Trukhanov and A.Trukhanov, Ceram. Int., 48, 24866 (2022)
