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In relation to this article, we declare that there is no conflict of interest.
Publication history
Received November 22, 2022
Revised December 19, 2022
Accepted December 31, 2022
Acknowledgements
This research was supported by the Korea Electric Power Corporation (R22EA08) and Korea Institute of Energy Technology Evaluation and Planning (2019281010007A)
articles This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Excellent physical durability and enhanced Fano absorption of SPR sensor platform based on Au-covered silica sphere monolayer

1Department of Chemical Engineering, University of Florida, Gainesville FL 32611, USA 2Energy and Environment Laboratory, Korea Electric Power Corp. Research Institute, Daejeon 34056, Korea 3New Energy Technologies Laboratory, Korea Electric Power Corp. Research Institute, Naju 58277, Korea
Korean Journal of Chemical Engineering, June 2023, 40(6), 1540-1547(8), 10.1007/s11814-023-1393-3
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Abstract

It is essential to secure the optical performance (sensitivity, FOM, plasmonic absorption strength, etc.), large-area fabrication, and physical durability to improve the usability of nanostructured SPR sensors. In this study, to ensure the physical durability of an Au-covered silica sphere monolayer (Au film over nanosphere (AuFON)) manufactured for use as an SPR sensor platform, the sensing performance and physical durability after TMOS treatment to bind spherical silica particles were investigated. The peel-off test showed that Au and silica constituting the AuFON did not fall off, and there was no significant difference in the sensing sensitivity and plasmonic absorption intensity before and after TMOS treatment. In addition, when colloidal Au nanoparticles (diameter of 5 nm) were applied to as-prepared AuFON and heat-treated, it was confirmed that the Au shells of the plasmonic particles were interconnected, and the Fano intensity increased from 3-5% to 22%

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