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Received November 2, 2022
Revised December 3, 2022
Accepted December 11, 2022
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Enhanced adsorption of cationic and anionic dyes using cigarette butt-based adsorbents: Insights into mechanism, kinetics, isotherms, and thermodynamics
Thi Kieu Ngan Tran1
Van Thuan Le1 2
Tien Hoang Nguyen3
Van Dat Doan4†
Yasser Vasseghian5 6 7†
Hoang Sinh Le8†
1The Faculty of Environmental and Natural Sciences, Duy Tan University, 03 Quang Trung, Da Nang, 550000, Viet Nam 2Center for Advanced Chemistry, Institute of Research and Development, Duy Tan University, 03 Quang Trung, Da Nang, 550000, Viet Nam 3The University of Da Nang, University of Science and Education, 459 Ton Duc Thang st., Lien Chieu, Da Nang 550000, Viet Nam 4Faculty of Chemical Engineering, Industrial University of Ho Chi Minh City, Ho Chi Minh City, Viet Nam 5Department of Chemistry, Soongsil University, Seoul 06978, South Korea 6University Centre for Research & Development, Department of Mechanical Engineering, Chandigarh University, Gharuan, Mohali, Punjab, 140413, India 7School of Engineering, Lebanese American University, Byblos, Lebanon 8VN-UK Institute for Research and Executive Education, University of Danang, Danang City 550000, Viet Nam
doanvandat@iuh.edu.vn, vasseghian@ssu.ac.kr, sinh.le@vnuk.edu.vn
Korean Journal of Chemical Engineering, July 2023, 40(7), 1650-1660(11), 10.1007/s11814-022-1373-z
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Abstract
The present study provides an eco-friendly and economical way to recycle discarded cigarette butts (CBs).
The raw CBs were treated with NaOH (CB-B) and integrated with chitosan (Cs), and further applied as an adsorbent
for the removal of synthetic dyes. Two common cationic dyes of methylene blue (MB) and crystal violet (CV) and one
anionic dye of reactive blue 19 (RB 19) were selected as model adsorbates. The study results revealed that CB-B showed
a high adsorption ability toward cationic dyes, while the CB-B/Cs composite exhibited a stronger affinity for the
anionic RB 19. The adsorption of all selected dyes onto CB-B and CB-B/Cs was a spontaneous exothermic process,
conforming to the pseudo-first-order kinetic and Langmuir isotherm models. The maximum adsorption capacities for
MB, CV and RB 19 at pH of 7, an adsorbent dosage of 4, and a temperature of 25 o
C were 89.85, 82.41, and 304.49 mg/
g, respectively. The primary adsorption mechanism was physical adsorption with the participation of electrostatic
attraction. The CB-based adsorbents displayed high reusability, maintaining more than 75% after four consecutive
cycles of reuse. This study demonstrates the promising application potential of CB-based adsorbents for treating synthetic dyes in wastewater. The conversion of CBs into a useful high-value material has special significance for environmental engineering
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2. Z. Li, Y. Xing, Y. Liu, A. Meng and X. Fan, RSC Adv., 12, 29878(2022).
3. R. Al-Tohamy, S. S. Ali, F. Li, K. M. Okasha, Y. A.-G. Mahmoud, T.Elsamahy, H. Jiao, Y. Fu and J. Sun, Ecotoxicol. Environ. Saf., 231,113160 (2022).
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14. K. Murugan, U. Suresh, C. Panneerselvam, R. Rajaganesh, M. Roni,A. T. Aziz, J.-S. Hwang, K. Sathishkumar, A. Rajasekar, S. Kumar,A. A. Alarfaj, A. Higuchi and G. Benelli, Environ. Sci. Pollut. Res.,25, 10456 (2018).
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23. L. Van Thuan, T. B. Chau, T. T. K. Ngan, T. X. Vu, D. D. Nguyen,M. H. Nguyen, D. T. T. Thao, N. To Hoai and L. H. Sinh, Environ.Technol. (United Kingdom), 39, 1745 (2018).
24. X. Xu, J. Yu, C. Liu, G. Yang, L. Shi and X. Zhuang, React. Funct.Polym., 160, 104840 (2021).
25. X. Zhao, X. Wang and T. Lou, J. Hazard. Mater., 403, 124054 (2021).
26. U. J. Kim, S. Kimura and M. Wada, Carbohydr. Polym., 214, 294(2019).
27. B. Shetty, Y. S. R and J. Johns, Res. Sq., 2022, 1 (2022).
28. Y. Wang, H. Wang, H. Peng, Z. Wang, J. Wu and Z. Liu, Fibers Polym., 19, 340 (2018).
29. A. Tehrim, M. Dai, X. Wu, M. M. Umair, I. Ali, M. A. Amjed, R.Rong, S. F. Javaid and C. Peng, J. Appl. Polym. Sci., 138, 1 (2021).
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32. E. Baladi, F. Davar and A. Hojjati-Najafabadi, Environ. Res., 215,114270 (2022).
33. Z. Qi, H. Lan, T. P. Joshi, R. Liu, H. Liu and J. Qu, RSC Adv., 6,66990 (2016).
34. C. Liang, Q. Shi, J. Feng, J. Yao, H. Huang and X. Xie, Nanomaterials, 12, 1814 (2022).
35. V. T. Le, V. D. Doan, D. D. Nguyen, H. T. Nguyen, Q. P. Ngo, T. K. N.Tran and H. S. Le, Water, Air, Soil Pollut., 229, 101 (2018).
36. Z. Esmaeili, S. Izadyar, Y. Hamzeh and A. Abdulkhani, J. Chem.Eng. Data, 66, 1068 (2021).
37. M. U. Dao, H. S. Le, H. Y. Hoang, V. A. Tran, V. D. Doan, T. T. N.Le, A. Sirotkin and V. T. Le, Environ. Res., 198, 110481 (2021).
38. C. C. Fu, H. N. Tran, X. H. Chen and R. S. Juang, J. Ind. Eng. Chem.,83, 235 (2020).
