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- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
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Received July 11, 2022
Revised November 24, 2022
Accepted December 16, 2022
- Acknowledgements
- This work was supported by the National Natural Science Foundation of China (Grant No. 42177032) and the National Key R&D Program of China (Grant No. 2018YFC1802005). We thank LetPub for its linguistic assistance during the preparation of this manuscript.
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Effect of manganese doping on the PbO2 electrode for the enhanced electrochemical oxidation of anthracene: Optimization and mechanism
1Key Laboratory of Soil Environment and Pollution Remediation, Institute of Soil Science, Chinese Academy of Sciences, Nanjing 210008, China 2University of Chinese Academy of Sciences, Beijing 100049, China
canglong@issas.ac.cn
Korean Journal of Chemical Engineering, July 2023, 40(7), 1686-1698(13), 10.1007/s11814-023-1379-1
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Abstract
Organic pollutant removal can be realized via electrochemical degradation, and anodic oxidation plays an
important role in the degradation process. However, the degradation process is hindered by low removal efficiency and
reusability. In this study, a PbO2 electrode and a Mn-doped PbO2 (Mn-PbO2) electrode were prepared via electrodeposition. Different from the traditional method of increasing the oxygen evolution potential (OEP) of PbO2 electrode,
such as introducing Ce, Bi, and La in PbO2 electrode, introducing Mn in PbO2 electrode promoted the generation of
strong oxidant MnO4
under electrolytic conditions to remove organic pollutants. The Mn-PbO2 electrode was used for
anthracene (ANT) degradation and the results showed that an ANT removal efficiency of 91.28% was achieved in
120 min under the most suitable operational variables, namely, a Na2SO4 concentration of 0.1 M, initial pH of 7, and
current density of 20 mA/cm2
. In addition, the ANT degradation mechanism was analyzed. Given that the Mn-PbO2
electrode exhibited better removal efficiency in the wide pH range and remarkable degradation efficiency compared
with the PbO2 electrode, the Mn-PbO2 electrode has practical application prospects for organic pollutant degradation.
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