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In relation to this article, we declare that there is no conflict of interest.
Publication history
Received September 19, 2022
Revised January 7, 2023
Accepted January 31, 2023
Acknowledgements
Vikneswary Rajendaren would like to express her gratitude to the Universiti Malaysia Pahang for sponsoring her Ph.D. study under the UMP Doctoral Research Scheme (DRS)
articles This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Effect of spinning parameter on the properties and performance of hollow fiber supported liquid membrane for levulinic acid extraction

Faculty of Chemical and Process Engineering Technology, Universiti Malaysia Pahang, Lebuhraya Tun Razak, 26300 Gambang, Pahang Darul Makmur, Malaysia
smsaufi@ump.edu.my
Korean Journal of Chemical Engineering, July 2023, 40(7), 1746-1759(14), 10.1007/s11814-023-1439-6
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Abstract

A hollow fiber-supported liquid membrane (HFSLM) configuration with a large membrane surface area per volume is becoming more viable and feasible to use on an industrial scale. However, the hollow fiber (HF) forms a thicker skin outer layer than its flat-sheet equivalents, resulting in lower membrane fluxes and more unsatisfactory performance. Therefore, this study investigated the effect of HF spinning parameters such as bore liquid type, air gap distance (3-12 cm), and air relative humidity (64-100 wt%) on the properties and performance of HFSLM for levulinic acid (LA) extraction. The HF membranes were characterized in terms of morphology, contact angle, porosity, and membrane tensile strength. Polyethersulfone-based HF membrane prepared using 60% v/v dimethylacetamide as bore liquid at 6 cm air gap distance and 86% air relative humidity resulted in the highest LA extraction of 72.2%. The membrane had a dual symmetric finger-like structure with an open porous structure. The value of the outer fiber surface contact angle, porosity, and tensile stress was 94.1o , 77.57%, and 1,524.7 kPa, respectively. An optimal spinning condition is crucial in producing the best HF structure for improving the HFSLM performance in LA extraction.

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