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- In relation to this article, we declare that there is no conflict of interest.
- Publication history
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Received August 13, 2022
Revised January 16, 2023
Accepted February 3, 2023
- Acknowledgements
- This work was supported by the Inner Mongolia Special Project for Transformation of Scientific and Technological Achievements [2019CG073], Solid Waste Resource National Key Research & Development Project [2020YFC1909105] and Major Science and Technology Project of Inner Mongolia Autonomous Region [2021ZD0016]. Key Project of Scientific and Technological Research in Colleges and Universities of Inner Mongolia Autonomous Region [NJZZ23056], Basic Scientific Research Business Fund Project of Universities Direc
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Effect of Cr2O3 on the viscosity and structure of slag (or glass) of CaO-MgO-Al2O3-SiO2 system
School of Materials and Metallurgy, Inner Mongolia University of Science and Technology, Baotou 014010, China
wangyici01060@163.com
Korean Journal of Chemical Engineering, July 2023, 40(7), 1783-1791(9), 10.1007/s11814-023-1432-0
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Abstract
The glass-ceramics of CaO-MgO-Al2O3-SiO2-Cr2O3 system was prepared by melting method using blast
furnace slag, low-carbon ferrochrome alloy slag and quartz sand as raw materials, and the effect of Cr2O3 on the viscosity and structure of slag (or glass) of CaO-MgO-Al2O3-SiO2 (CMAS) system at high temperature was studied. The
Urbain viscosity prediction model was established and optimized, and the effect of Cr2O3 on the structure of slag (or
glass) was studied by Raman spectroscopy. The results show that when the mass fraction of Cr2O3 is in the range of
0.85-2.05%, the viscosity of slag (or glass) of CMAS system decreases with the increase of Cr2O3 content. The average
relative errors between the experimented viscosity value and the calculated viscosity value obtained by using the optimized Urbain model are less than 20%, which is effective and universal for the viscosity prediction of slag (or glass) of
CaO-MgO-Al2O3-SiO2-Cr2O3 system. With the increase of Cr2O3 content, the complex silicon oxygen tetrahedrons
(Q3) disintegrate into a larger number of simple silicon oxygen tetrahedrons (Q0, Q1, Q2), resulting in the sparse structure of the melt network and a decrease in macroscopic viscosity.
References
1. D. Gao, F. P. Wang, Y. T. Wang and Y. N. Zeng, Sustainability, 12(2020).
2. M. Rathore and A. Dalvi, Indian J. Pure Ap. Phy., 51, 372 (2013).
3. W. X. Shang, Z. W. Peng, Y. W. Huang, F. Q. Gu, J. Zhang, H. M.Tang, L. Yang, W. G. Tian, M. J. Rao, G. H. Li and T. Jiang, J. Cleaner Production, 317 (2021).
4. H. T. Gao, X. H. Liu, J. Q. Chen, J. L. Qi, Y. B. Wang and Z. R. Ai,Ceram. Int., 44, 6044 (2018).
5. B. E. Yekta and P. Alizadeh, Glass Technol., 46, 347 (2005).
6. W. Zhao, X. F. Huang, B. J. Yan, S. Y. Hu, H. W. Guo and D. Chen,Sustainability-basel, 13 (2021).
7. J. Chang, H. J. Li, K. D. Zheng, C. G. Liu, L. M. Wang, B. Li, X. N.Bu and H. Z. Shao, Physicochem. Probl. Mi., 56, 460 (2020).
8. L. B. Deng, S. Wang, Z. Zhang, Z. H. Li, R. D. Jia, F. Yun, H. Li,Y. H. Ma and W. C. Wang, Mater. Chem. Phys., 251 (2020).
9. W. J. Duan, Q. B. Yu, J. X. Liu, K. Wang, H. Q. Xie, Q. Qin and Z. C. Han, Ironmak Steelmak, 43, 730 (2016).
10. X. J. Dong, H. Y. Sun, X. F. She, Q. G. Xue and J. S. Wang, Ironmak Steelmak, 41, 99 (2014).
11. Z. Li, Z. W. Luo, X. Y. Li, T. Y. Liu, L. M. Guan, T. Wu and A. X.Lu, J. Porous. Mat., 23, 231 (2016).
12. A.Y. Kolobov and G.A. Sycheva, Glass Phys. Chem+, 46, 249 (2020).
13. W. X. Dong, Q. F. Bao, J. E. Zhou, T. G. Zhao, K. Liu, S. Z. Li, S. Y.Liu and K. X. Ma, J. Ceram. Soc. Jpn., 128, 821 (2020).
14. D. Di Genova, J. Vasseur, K. U. Hess, D. R. Neuville and D. B. Dingwell, J. Non-cryst Solids, 470, 78 (2017).
15. R. Z. Xu, J. L. Zhang, Z. Y. Wang and K. X. Jiao, Steel Res. Int., 88 (2017).
16. T. L. Tian, Y. Z. Zhang, H. W. Xing, J. Li and Z. Q. Zhang, High Temp. Mat. Pr-isr, 37, 33 (2018).
17. I. Vilciu, Metal Int., 18, 126 (2013).
18. G. Urbain, Y. Bottinga and P. Richet, Geochimica Et Cosmochimica Acta, 46 (1982).
19. P. V. Riboud, Y. Roux, L. D. Lucas and H. Gaye, Huettenprax. Metallweiterverarb, 19, 859 (1981).
20. K. C. Mills and S. Sridhar. Ironmaking & Steelmaking, 26, 262 (1999).
21. T. Iida, H. Sakai, Y. Kita and K. Shigeno, High Temp. Mat. Pr-isr,19, 153 (2000).
22. H. Masai, B Chem. Soc. Jpn., 91, 950 (2018).
23. R. Wang and B. M. Zhang, Spectrosc. Spectanal, 30, 376 (2010).
24. C. Balachandran, J. F. Munoz and T. Arnold, Cement Concrete Res.,92, 66 (2017).
25. S. Das, A. Madheshiya, S. S. Gautam and C. R. Gautam, J. NonCryst. Solids, 478, 16 (2017).
26. Y. Shi, B. W. Li, M. Zhao and M. X. Zhang, J. Am. Ceram. Soc., 101,3968 (2018).
27. H. Ko, M. Kim, S. M. Park and H. M. Lim, J. Eur. Ceram. Soc., 58,160 (2021).
28. V. O. Sinelnikov and D. Kalisz, Glass Ceram+, 73, 144 (2016).
29. L. Forsbacka and L. Holappa, Scand J. Metall, 33, 261 (2004).
30. R. Z. Xu, J. L. Zhang, Z. Y. Wang and K. X. Jiao, Steel Res. Int., 88(2017).
31. H. S. Ray and S. Pal, Ironmak Steelmak, 31, 125 (2004).
32. A. S. Kirichenko and S. M. Nekhamin, Metallurgist+, 64, 548 (2020).
33. H. Y. Zheng, Y. Q. Ding, S. F. Zhou, S. F. Zhou, Q. L. Wen, X. Jiang,Q. J. Gao and F. M. Shen, Steel Res. Int., 92 (2021).
34. D. Kalisz, Arch Metall Mater, 59, 149 (2014).
35. R. Z. Xu, J. L. Zhang, Z. Y. Wang and K. X. Jiao, Steel Res. Int., 88(2017).
36. C. Y. Xu, C. Wang, R. Z. Xu and J. L. Zhang, Int. J. Min. Met. Mater.,28, 797 (2021).
37. T. Wu, Y. L. Zhang, F. Yuan and Z. Q. An, Metall Mater Trans B,49, 1719 (2018).
38. C. Han, M. Chen, W. D. Zhang, Z. X. Zhao, T. Evans, A. V. Nguyen and B. J. Zhao, Steel Res. Int., 86, 678 (2015).
39. H. Ko, M. Kim and S. M. Park, J. Eur. Ceramsoc., 58, 160 (2021).
40. Y. Q. Wu, G. C. Jiang and J. L. You, J. Chem. Phys., 121, 7883 (2004).
41. W. N. Li, R. Luo and C. Li, J. Non-Cryst. Solids, 449, 119 (2016).
42. F. Schiavi, N. Bolfan-Casanova and A. C. Withers, Chem. Geol., 483,312 (2018).
43. G. R Kumar and M. C. Rao, Optik, 181, 721 (2019).
44. B. W. Li, L. B. Deng and X. F. Zhang, J. Non-Cryst. Solids, 380, 103(2013).
45. M. V. S. Rao, C. Rajyasree and T. Narendrudu, Opt. Mater., 47, 315(2015).
46. S. L. Ou-Yanga, B. W. Li and X. F. Zhang, Optoelectron Adv. Mat., 9(2015).
47. A. M. Welsch, J. L. Knipping and H. Behrens, J. Non-Cryst. Solids,471, 98 (2017).
48. M. Lesniak, J. Partyka and M. Sitarz, Phys. Chem. Glasses-B, 58, 1(2017).
2. M. Rathore and A. Dalvi, Indian J. Pure Ap. Phy., 51, 372 (2013).
3. W. X. Shang, Z. W. Peng, Y. W. Huang, F. Q. Gu, J. Zhang, H. M.Tang, L. Yang, W. G. Tian, M. J. Rao, G. H. Li and T. Jiang, J. Cleaner Production, 317 (2021).
4. H. T. Gao, X. H. Liu, J. Q. Chen, J. L. Qi, Y. B. Wang and Z. R. Ai,Ceram. Int., 44, 6044 (2018).
5. B. E. Yekta and P. Alizadeh, Glass Technol., 46, 347 (2005).
6. W. Zhao, X. F. Huang, B. J. Yan, S. Y. Hu, H. W. Guo and D. Chen,Sustainability-basel, 13 (2021).
7. J. Chang, H. J. Li, K. D. Zheng, C. G. Liu, L. M. Wang, B. Li, X. N.Bu and H. Z. Shao, Physicochem. Probl. Mi., 56, 460 (2020).
8. L. B. Deng, S. Wang, Z. Zhang, Z. H. Li, R. D. Jia, F. Yun, H. Li,Y. H. Ma and W. C. Wang, Mater. Chem. Phys., 251 (2020).
9. W. J. Duan, Q. B. Yu, J. X. Liu, K. Wang, H. Q. Xie, Q. Qin and Z. C. Han, Ironmak Steelmak, 43, 730 (2016).
10. X. J. Dong, H. Y. Sun, X. F. She, Q. G. Xue and J. S. Wang, Ironmak Steelmak, 41, 99 (2014).
11. Z. Li, Z. W. Luo, X. Y. Li, T. Y. Liu, L. M. Guan, T. Wu and A. X.Lu, J. Porous. Mat., 23, 231 (2016).
12. A.Y. Kolobov and G.A. Sycheva, Glass Phys. Chem+, 46, 249 (2020).
13. W. X. Dong, Q. F. Bao, J. E. Zhou, T. G. Zhao, K. Liu, S. Z. Li, S. Y.Liu and K. X. Ma, J. Ceram. Soc. Jpn., 128, 821 (2020).
14. D. Di Genova, J. Vasseur, K. U. Hess, D. R. Neuville and D. B. Dingwell, J. Non-cryst Solids, 470, 78 (2017).
15. R. Z. Xu, J. L. Zhang, Z. Y. Wang and K. X. Jiao, Steel Res. Int., 88 (2017).
16. T. L. Tian, Y. Z. Zhang, H. W. Xing, J. Li and Z. Q. Zhang, High Temp. Mat. Pr-isr, 37, 33 (2018).
17. I. Vilciu, Metal Int., 18, 126 (2013).
18. G. Urbain, Y. Bottinga and P. Richet, Geochimica Et Cosmochimica Acta, 46 (1982).
19. P. V. Riboud, Y. Roux, L. D. Lucas and H. Gaye, Huettenprax. Metallweiterverarb, 19, 859 (1981).
20. K. C. Mills and S. Sridhar. Ironmaking & Steelmaking, 26, 262 (1999).
21. T. Iida, H. Sakai, Y. Kita and K. Shigeno, High Temp. Mat. Pr-isr,19, 153 (2000).
22. H. Masai, B Chem. Soc. Jpn., 91, 950 (2018).
23. R. Wang and B. M. Zhang, Spectrosc. Spectanal, 30, 376 (2010).
24. C. Balachandran, J. F. Munoz and T. Arnold, Cement Concrete Res.,92, 66 (2017).
25. S. Das, A. Madheshiya, S. S. Gautam and C. R. Gautam, J. NonCryst. Solids, 478, 16 (2017).
26. Y. Shi, B. W. Li, M. Zhao and M. X. Zhang, J. Am. Ceram. Soc., 101,3968 (2018).
27. H. Ko, M. Kim, S. M. Park and H. M. Lim, J. Eur. Ceram. Soc., 58,160 (2021).
28. V. O. Sinelnikov and D. Kalisz, Glass Ceram+, 73, 144 (2016).
29. L. Forsbacka and L. Holappa, Scand J. Metall, 33, 261 (2004).
30. R. Z. Xu, J. L. Zhang, Z. Y. Wang and K. X. Jiao, Steel Res. Int., 88(2017).
31. H. S. Ray and S. Pal, Ironmak Steelmak, 31, 125 (2004).
32. A. S. Kirichenko and S. M. Nekhamin, Metallurgist+, 64, 548 (2020).
33. H. Y. Zheng, Y. Q. Ding, S. F. Zhou, S. F. Zhou, Q. L. Wen, X. Jiang,Q. J. Gao and F. M. Shen, Steel Res. Int., 92 (2021).
34. D. Kalisz, Arch Metall Mater, 59, 149 (2014).
35. R. Z. Xu, J. L. Zhang, Z. Y. Wang and K. X. Jiao, Steel Res. Int., 88(2017).
36. C. Y. Xu, C. Wang, R. Z. Xu and J. L. Zhang, Int. J. Min. Met. Mater.,28, 797 (2021).
37. T. Wu, Y. L. Zhang, F. Yuan and Z. Q. An, Metall Mater Trans B,49, 1719 (2018).
38. C. Han, M. Chen, W. D. Zhang, Z. X. Zhao, T. Evans, A. V. Nguyen and B. J. Zhao, Steel Res. Int., 86, 678 (2015).
39. H. Ko, M. Kim and S. M. Park, J. Eur. Ceramsoc., 58, 160 (2021).
40. Y. Q. Wu, G. C. Jiang and J. L. You, J. Chem. Phys., 121, 7883 (2004).
41. W. N. Li, R. Luo and C. Li, J. Non-Cryst. Solids, 449, 119 (2016).
42. F. Schiavi, N. Bolfan-Casanova and A. C. Withers, Chem. Geol., 483,312 (2018).
43. G. R Kumar and M. C. Rao, Optik, 181, 721 (2019).
44. B. W. Li, L. B. Deng and X. F. Zhang, J. Non-Cryst. Solids, 380, 103(2013).
45. M. V. S. Rao, C. Rajyasree and T. Narendrudu, Opt. Mater., 47, 315(2015).
46. S. L. Ou-Yanga, B. W. Li and X. F. Zhang, Optoelectron Adv. Mat., 9(2015).
47. A. M. Welsch, J. L. Knipping and H. Behrens, J. Non-Cryst. Solids,471, 98 (2017).
48. M. Lesniak, J. Partyka and M. Sitarz, Phys. Chem. Glasses-B, 58, 1(2017).
