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- In relation to this article, we declare that there is no conflict of interest.
- Publication history
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Received October 1, 2022
Revised February 11, 2023
Accepted February 27, 2023
- Acknowledgements
- This work was supported by the Scientific and Technological Research Council of Turkey (TUBITAK) grant numbers 119M433 and 118C143.
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Sustainable production of acrolein over highly stable and selective WO3 over SiO2-TiO2 catalysts
Istanbul University-Cerrahpaşa, Faculty of Engineering, Chemical Engineering Department, Avcılar, 34320 Istanbul, Turkey
Korean Journal of Chemical Engineering, August 2023, 40(8), 1882-1891(10), 10.1007/s11814-023-1406-2
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Abstract
The effects of the addition of colloidal silica (cSiO2) and solvents used in the catalyst preparation on the
activity and stability of WO3-TiO2 catalysts are reported in this paper. The highly stable and selective WO3 supported
cSiO2-TiO2 catalysts were prepared and tested in the vapor-phase glycerol oxy-dehydration. WO3-TiO2 catalysts with
and without cSiO2 were characterized by XRD, SEM, NH3-TPD, infrared spectroscopy of pyridine (FTIR-Py), XPS,
RAMAN, and N2 adsorption-desorption (BET). The highest medium strength acidity and optimum Brønsted to Lewis
acid site ratio of WO3 catalysts were achieved upon the addition of colloidal silica (cSiO2) onto TiO2 support. The
medium strength acidity of Brønsted acid sites was responsible for the improved acrolein selectivity and stability. The
other major factors in glycerol conversion and acrolein selectivity were the glycerol content and liquid hourly space
velocity. The yield to acrolein was up to 70% and kept almost constant in a 50 h continuous run at 300 o
C. The gradual
decrease in glycerol conversion was due to the build-up of oxygen-containing carbonaceous materials deposited on the
catalyst surface.
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4. M. Checa, S. Nogales-Delgado, V. Montes and J. M. Encinar, Catalysts, 10, 1 (2020).
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34. A. M. Hirt, J. Phys. Chem., 95, 991 (1991).
35. P. Lauriol-Garbay, J. M. M. Millet, S. Loridant, V. Bellire-Baca and P. Rey, J. Catal., 280, 68 (2011).
36. X. C. Jiang, C. H. Zhou, R. Tesser, M. Di Serio, D. S. Tong and J. R.Zhang, Ind. Eng. Chem. Res., 57, 10736 (2018).
37. F. Cavani, S. Guidetti, L. Marinelli, M. Piccinini, E. Ghedini and . Signoretto, Appl. Catal. B Environ., 100, 197 (2010).
38. T. Ma, Z. Yun, W. Xu, L. Chen, L. Li, J. Ding and R. Shao, Chem.Eng. J., 294, 343 (2016).
39. M. Akizuki and Y. Oshima, Ind. Eng. Chem. Res., 51, 12253 (2012).
40. A. Talebian-Kiakalaieh and N. A. S. Amin, Chem. Eng. Trans., 56,655 (2017).
41. A. Chieregato, M. D. Soriano, F. Basile, G. Liosi, S. Zamora, P. Concepción, F. Cavani and J. M. López Nieto, Appl. Catal. B Environ.,
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43. J.-L. Dubois, K. Okumura, Y. Kobayash and R. Hiraoka, Improved Process of Dehydration Reactions, WO2013017904 (2013).
44. J.-L. Dubois, Method for Synthesis of Acrolein from Glycerol US 2010/0274038A1 (2010).
45. R. Znaiguia, L. Brandhorst, N. Christin, V. Bellière Baca, P. Rey,J. M. M. Millet and S. Loridant, Micropor. Mesopor. Mater., 196, 97 (2014).
