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Language: English

Conflict of Interest: In relation to this article, we declare that there is no conflict of interest.

Publication history: Received January 26, 2023
Revised April 19, 2023
Accepted May 1, 2023

Acknowledgements: This work was supported by Jilin Province Science and Technology Department Project (20210508026RQ; 20220508026RC) and Jilin Province Development and Reform Commission Project (2022C040).

This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.

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Strong, and recyclable thermosets cross-linked by MWCNT/poly(aryl ether ketone) containing furan based on Diels-Alder cycloaddition

Yongpeng Wang¹ Heng Wang¹ Qingwen Zhang¹ Yingyuan Zhang¹ Pengtao Yan² Mengzhu Liu^{1 3†} Haibo Zhang³

¹College of Materials Science and Engineering, Jilin Institute of Chemical Technology, Jilin 132022, China ²Sinodentex Co., Ltd, Changchun, China ³College of Chemistry, National & Local Joint Engineering Laboratory for Synthesis Technology of High Performance Polymer, Jilin University, Changchun 130012, China

liumengzhu125@163.com

Korean Journal of Chemical Engineering, August 2023, 40(8), 2026-2034(9), 10.1007/s11814-023-1481-4

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Abstract

Multi-walled carbon nanotube (MWCNT)/poly(aryl ether ketone) networks cross-linked by Diels-Alder cycloaddition possess outstanding mechanical and rheological properties. Poly(aryl ether ketone) containing pendant furan (PAEK-Fu) was synthesized, which had excellent thermal and mechanical properties, and a series of cross-linked materials with reversible covalent cross-linked crosslinking network were synthesized through a furan/MWCNTs DielsAlder (D-A) reaction between PAEK-Fu and MWCNTs. Thermal and mechanical properties for MWCNT/PAEK-Fu composites were studied, and after crosslinking, MWCNT/PAEK-Fu composites exhibited good flexibility and resistance against organic solvents. After heating to 180 o C, the cross-linked MWCNT/PAEK-Fu composite membranes could be dissolved in NMP. This work demonstrates that the poly(aryl ether ketone)s can be made into recyclable thermoset materials using the concept of associative dynamic bonding. Given the dramatically increasing interest in environmentally sustainable materials, this MWCNT/poly(aryl ether ketone) interaction mode provides a robust approach to high performance engineering plastics with improved performance compared with the thermoplastic counterparts

Keywords

Poly(aryl ether ketone) Multi-walled Carbon Nanotubes Recyclable Thermosets Composites

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