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- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received March 2, 2023
Revised May 15, 2023
Accepted June 9, 2023
- Acknowledgements
- This work was supported by the Korea Evaluation Institute of Industrial Technology (KEIT) through the Carbon Cluster Construction project [10083621, Development of Preparation Technology in Petroleum-Based Artificial Graphite Anode] and Technology Innovation Program [20006696, Development of isotropic graphite block for semiconductor process] funded by the Ministry of Trade, Industry & Energy (MOTIE, Korea).
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Electrochemical property based on the structural control of pitch-based carbon anode
1C1 Gas & Carbon Convergent Research Center, Korea Research Institute of Chemical Technology, 141 Gajeong-ro, Yuseong-gu, Daejeon 34114, Korea 2Department of Chemical Engineering, Chungbuk National University, 1 Chungdae-ro, Seowon-gu, Cheongju, Chungbuk 28644, Korea 3Advanced Materials and Chemical Engineering, University of Science and Technology (UST), 217, Gajeong-ro, Yuseong-gu, Daejeon 34113, Korea
jsim@krict.re.kr, jdlee@chungbuk.ac.kr
Korean Journal of Chemical Engineering, September 2023, 40(9), 2165-2173(9),
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Abstract
The charge/discharge characteristics of a carbon anode were studied in a lithium ion battery system based
on the effects of a graphite structure developed by heat energy. A carbon precursor (pitch) was synthesized from pyrolysis of fuel oil, after which a carbonization/graphitization treatment at 1,000-2,400 o
C was carried out on the carbon
anode. The lithium storage mechanism of carbonized materials treated under 1,300 o
C was noted not by the space
between the graphite layers but the cavity in the carbon materials. This indicates higher capacity and high speed
charge-discharge performance capabilities than graphite. For graphitized materials treated at 2,400 o
C, lithium ions are
mainly inserted between the layers of the graphite, forming an interlayer structure. Based on the suggested mechanisms, it is noted that the charge/discharge of lithium ions can be controlled based on control of the graphite stru
Keywords
References
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28. K. Tokumitsu, H. Fujimoto, A. Mabuchi and T. Kasuh, Carbon,37(10), 1599 (1999).
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