Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received October 11, 2022
Revised March 13, 2023
Accepted March 25, 2023
- Acknowledgements
- The authors express their great appreciation for the financial support of this project by the National Natural Science Foundation of China (51676081), Wuhan Enterprise Technology Innovation Projects (2019020702011359; 2020020602012150), and the 111 Project B17019. Additionally, the authors would like to thank the Shiyanjia Lab (www.shiyanjia.com) for the support of SEM and NH3- TPD tests.
- This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
All issues
Hydrogen production by catalytic steam reforming of waste cooking oil over La-Ni/ZSM-5 catalyst
Abstract
Ni/ZSM-5 catalyst is one of the promising catalysts to improve the catalytic steam reforming of waste cooking oil (WCO) for hydrogen production. Furthermore, the introduction of lanthanum (La) plays a huge role in inhibiting metal sintering and carbon deposition and improving the stability and activity of the catalyst. This study investigated
the effects of reaction temperature (600-800 o
C), steam to carbon molar ratio (S/C), n Ni/ZSM-5 (n=5, 10, and 15 wt%),
and the addition of promoter (La) on the experimentally generated hydrogen yield and carbon deposition. Results
showed that the experiment used 6 wt% La-10 wt% Ni/ZSM-5 at 0.1 MPa, 700 o
C, space-time ()=0.56 gcatalysth/gWCO,
and S/C=5.25, which obtained the yield of H2 was 154.12 mol/kg, carbon deposition was 5.38%. Therefore, Ni-modified catalyst added La to improve the catalyst coking resistance and prevent carbon formation. Moreover, La can further promote the dispersion of nickel on the surface of the carrier and improve the catalytic performance of the catalyst
for steam reforming reaction.
Keywords
References
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