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Received October 5, 2022
Revised December 25, 2022
Accepted January 31, 2023
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Bio-based composite as phase change material including spent coffee grounds and beeswax paraffin
1Laboratoire de Sciences des Matériaux et de l’Environnement (LMSE), Université de Sfax, Tunisi 2Laboratoire des Matériaux Multifonctionnels et Applications (LaMMA), Université de Sfax, Tunisia 3University of Technology and Applied Sciences - Sohar, P.O. Box: 135, Postal Code:311, Sohar, Sultanate of Oman 4Division of Engineering Materials (KMAT), Linköping University, 581 83, Sweden
abdotrg@yahoo.fr, makki.abdmouleh@yahoo.fr
Korean Journal of Chemical Engineering, September 2023, 40(9), 2342-2355(14), 10.1007/s11814-023-1448-5
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Abstract
New types of bio-composite phase change materials (BCPCM) with improved thermal properties were
made from spent ground coffee powder (C), beeswax (W) and low density polyethylene (LDPE). Beeswax is a relatively accessible phase change material of organic origin, with a significantly lower unit price compared to conventional phase change materials (PCM). The observations by SEM and FTIR spectroscopy showed that the BCPCMs
were physically combined. Through these techniques, it was discovered that ground coffee was effectively impregnated
with natural wax and LDPE. According to the thermal gravimetric analysis (TGA), the thermal stability of BCPCM
was improved, due to the use of waste coffee grounds, in the working temperature range. The biocomposite possesses
excellent performance as characterized by 136.9 J/g (W70C10PE20)>, 127.31 J/g (W70C20PE10)>, 126.95 J/g (W70C30)>,
121.08 J/g (W70PE30) of latent heat storage and tends to decrease the supercooling degree as compared with pure
beeswax during melting/solidification process. By adding LDPE to the PCM, the melting time is reduced, demonstrating an improvement in thermal energy storage (TES) reaction time to the demand. The experimental results showed
that the fraction of oils (12%) in spent ground coffee powder can participate in the improvement of the thermal properties of BCPMC. The use of biocompatible PCM by-products is suitable for applications in the field of heat storage
because it is affordable and environmentally beneficial.
Keywords
References
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2. A. Putra, K. H. Or, M. Z. Selamat, M. J. M. Nor, M. H. Hassan and I. Prasetiyo, Appl. Acoust., 136, 9 (2018).
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4. A. Trigui, M. Karkri, C. Boudaya, Y. Candau and L. Ibos, Compos.Part B Eng., 49, 22 (2013).
5. C. Moulahi, A. Trigui, C. Boudaya and M. Karkri, J. Therm. Compos. Mater., 30 (2017).
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7. G. Alva, Y. Lin, L. Liu and G. Fang, Energy Build., 144, 276 (2017).
8. C. Moulahi, A. Trigui, M. Karkri and C. Boudaya, Compos. Struct.,149, 69 (2016).
9. I. Chriaa, A. Trigui, M. Karkri, I. Jedidi, M. Abdelmouleh and C.Boudaya, Appl. Therm. Eng., 171, 115072 (2020).
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41. S. Takeshita and S. Yoda, Chem. Mater., 27, 7569 (2015).
42. A. El Kadib, ChemSusChem, 8, 217 (2015).
43. L. Boussaba, A. Foufa, S. Makhlouf, G. Lefebvre and L. Royon,Constr. Build. Mater., 185, 156 (2018).
44. H. Essabir, M. Raji, S. A. Laaziz, D. Rodrique, R. Bouhfid and A. el kacem Qaiss, Compos. Part B Eng., 149, 1 (2018).
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50. D. J. Lyman, R. Benck, S. Dell, S. Merle and J. Murray-Wijelath, JAgric. Food Chem., 51, 3268 (2003).
51. A. E. Atabani, S. Shobana, M. N. Mohammed, G. Uğuz, G. Kumar,
S. Arvindnarayan, M. Aslam and A. H. Al-Muhtaseb, Fuel, 244,419 (2019).
52. A. Bucio, R. Moreno-Tovar, L. Bucio, J. Espinosa-Dávila, F. Anguebes-Franceschi, Coatings, 11, 261 (2021).
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54. H. Vahabi, M. Jouyandeh, T. Parpaite, M. R. Saeb and S. Ramakrishna, Coatings, 11, 1021 (2021).
55. A. Abdelkhalik, H. Elsayed, M. Hassan, M. Nour, A. B. Shehata and M. Helmy, Egypt. J. Pet., 27, 131 (2018).
56. A. Trigui, M. Karkri, L. Peña, C. Boudaya, Y. Candau, S. Bouffi and F. Vilaseca, J. Compos. Mater., 47, 1387 (2013).
57. T. Qian, J. Li, X. Min, Y. Deng, W. Guan and H. Ma, Energy, 82,333 (2015).
58. M. H. Zahir, M. M. Rahman, K. Irshad, M. M. Rahman, Nanomaterials, 9, 1773 (2019).
59. I. Chriaa, M. Karkri, A. Trigui, I. Jedidi, M. Abdelmouleh and C.Boudaya, Polymer, 212, 123128 (2021).
60. G. R. Solomon, S. Karthikeyan and R. Velraj, Appl. Therm. Eng.,52, 505 (2013).
61. A. Nejman, E. Gromadzińska, I. Kamińska and M. Cieślak, Molecules, 25, 122 (2020).
62. A. Trigui, M. Karkri, C. Boudaya, Y. Candau, L. Ibos and M. Fois,J. Compos. Mater., 48, 49 (2014).
63. A. Trigui, M. Abdelmouleh and C. Boudaya, RSC Adv., 12, 21990 (2022)
