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In relation to this article, we declare that there is no conflict of interest.
Publication history
Received May 16, 2024
Accepted August 14, 2024
articles This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Effects of Hydrothermal Carbonization Process Parameters on Physicochemical Properties and Combustion Behavior of Maize Stalk Hydrochars

School of Metallurgical Engineering , Anhui University of Technology 1Shanghai Meishan Iron and Steel Limited by Share Ltd
zhangyingyi@ahut.edu.cn
Korean Journal of Chemical Engineering, October 2024, 41(11), 3035-3051(17), https://doi.org/10.1007/s11814-024-00265-4

Abstract

Hydrothermal carbonization (HTC) is an eff ective method to improve the performance of biomass fuels. In this work, the

reusable maize stalk (MS) hydrochars were prepared at diff erent carbonization conditions, and the eff ects of carbonization

parameters on physicochemical properties, recovery rate, coalifi cation mechanism and combustion behavior of MS hydrochars

were investigated. The results show that with the increase of temperature and time, the particle size, O/C and H/C ratios,

fl ammability index and comprehensive combustion characteristic index of MS hydrochars decrease gradually, while the

calorifi c value, ignition temperature ( T i ), and burnout temperature ( T f ) increase gradually. The combustibility and combustion

reactivity of MS hydrochars are signifi cantly better than anthracite. Under the optimal carbonization conditions (260 ºC,

40 min, solid–liquid ratio of 2%), MS hydrochar has a high carbon content and calorifi c value, and the carbon content and

calorifi c value of MS are 66.85 and 22.36 MJ·kg −1 , respectively. HTC technology can eff ectively transform MS biomass

into high energy density solid fuel, which provides a theoretical basis for expanding the application fi eld of hydrochars.

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