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Characterization and Formation of Porous Hydroxyethyl Cellulose Membranes via Gas-Based Permeation: A Structural and Thermal Analysis
Abstract
This research explores the fabrication of porous Hydroxyethyl Cellulose (HEC) membranes, characterized by their inherent
mechanical strength and freedom from additional additives. Employing a gas-based method, a 200-μm HEC fi lm was
cast and its permeance was examined under varying gas pressures. The experimental process involved systematic pressure
increments, revealing the formation of pores due to solvent evaporation during the drying phase and the subsequent weakening
of intermolecular bonds. As gas pressure increased, both the number and size of pores exhibited signifi cant growth,
establishing pressure as a critical factor infl uencing pore characteristics. Structural analysis through Fourier Transform
Infrared (FT-IR) spectroscopy demonstrated no chemical alterations during gas permeation, confi rming that pore formation
was purely a physical phenomenon. FT-IR further identifi ed specifi c peaks corresponding to the molecular structure
of HEC. Deconvolution analysis of the FT-IR data highlighted the absence of chemical changes in the ether and hydroxyl
functional groups, reaffi rming the physical nature of pore formation. Thermogravimetric Analysis (TGA) was employed to
assess thermal stability, revealing that HEC fi lms remained stable even at temperatures exceeding 300 °C. Notably, fi lms
subjected to the gas permeation process exhibited more rapid degradation, signifying alterations in their physical properties
due to pore formation.