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Facile Hydrothermally Synthesized 2D-Based rGO/NiO Nanohybrid for Environmental Remediation of Malachite Green Pollutant

Department of Chemistry, Faculty of Science , Taif University , P.O. Box 11099 , Taif 21944 , Saudi Arabia 1Institute of Physics , Khwaja Fareed University of Engineering and Information Technology , Abu Dhabi Road , Rahim Yar Khan 64200 , Pakistan 2Department of Physics , Government Graduate College Taunsa Sharif , Dera Ghazi Khan 32100 , Pakistan
salma.physics.kfu@gmail.com
Korean Journal of Chemical Engineering, February 2024, 41(2), 503-513(11), https://doi.org/10.1007/s11814-024-00083-8

Abstract

This study produced rGO/NiO nanohybrid through a simple hydrothermal strategy for photocatalytic degradation of noxious

malachite green (MG) pollutants. Nanocomposites’ chemical structure was verifi ed by X-ray diff raction (XRD), ultraviolet

visible spectroscopy (UV–Vis. Spectroscopy), X-ray photoelectron spectroscopy (XPS) analysis and Raman spectra. Bandgap

narrowing of nickel oxide was observed by UV–Visible spectroscopy after its integration with rGO. In terms of photocatalytic

effi ciency, rGO/NiO nanocomposites show remarkable effi ciency (96.15%) in degrading malachite green dye than NiO

(81.73%) under 120 min. rGO/NiO nanocomposites exhibit a 0.006 min −1 rate constant, which is 2% greater than bare nickel

oxide. The scavenging analysis demonstrated that hydroxyl radicals and superoxide ion play a vital role in photodegradation.

The photocatalyst’s repeatability was determined through a cyclic test. The remarkable photocatalytic effi ciency was obtained

due to the synergetic behavior of rGO and NiO. rGO provided a greater surface area exhibiting greater number of active

zones responsible for the adsorption of electrolyte ions. This rGO/NiO nanohybrid has been employed as a photocatalyst in

effi ciently removing noxious pollutants from wastewater.

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