Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received October 15, 2023
Accepted December 13, 2023
- This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
All issues
Improving the Storage Stability of Coal Water Slurries Use of a pH-Responsive Thickener
Abstract
Coal water slurries (CWSs) are considered to be a new form of fuel that can alleviate the environmental and safety issues
associated with use of bulk solid fuel. However, CWSs does not always fi t into existing solid fuel supply and storage chain.
In this study, a novel method to control CWSs viscosity using pH-responsive thickener was proposed, off ering the advantages
of improved storage stability and on-demand viscosity control, thus allowing CWSs to be used as a c for a variety of applications.
This study investigates the eff ects of additives and pH on the viscosity and storage stability of CWSs. Poloxamer 407,
polynaphthalene sulfonate formaldehyde (PNSF), and a copolymer containing pigment-affi nic (PA) groups were used as
dispersants to lower CWSs viscosity. Xanthan gum, a modifi ed acrylic polymer (MAP), and carbomer were used as thickeners
for assessing the storage stability and fl uidity of CWSs based on viscosity changes. Optimal viscosity reduction was achieved
by the addition of PA. A viscosity of 7000 cP was achieved by the use of carbomer, with small amount comparable to 27.3
wt% of MAP and 22.7 wt% of Xanthan gum. Moreover, the carbomer-containing CWSs exhibited high storage stability in
a 360-h stability test, retaining 84.3% of the original baseline coal content. pH-dependent viscosity changes were observed
only in carbomer-containing samples.
References
2. U.S. EIA, Country analysis executive summary: India. U.S.
Energy Information Administration, Independent Statistic &
Analysis, p. 9 (2021)
3. H. Zhu, X. Yan, J. Xia, Y. Li, Preparation and rheological properties
of oil-water- coal triplex synfuel using petroleum sulfonate
as the dispersants. Fuel Process. Technol. 88 , 221–225 (2007).
https:// doi. org/ 10. 1016/j. fuproc. 2004. 11. 020
4. K. Aiuchi, R. Moriyama, S. Takeda, S. Kitada, M. Onozaki,
Y. Katayama, A pre-heating vaporization technology of coalwater-
slurry for the gasifi cation process. Fuel Process. Technol.
88 , 325–331 (2007). https:// doi. org/ 10. 1016/j. fuproc. 2004. 10.
010
5. J. Zhu, G. Zhang, G. Liu, Q. Qu, Y. Li, Investigation on the rheological
and stability characteristics of coal-water slurry with long
side-chain polycarboxylate dispersant. Fuel Process. Technol. 118 ,
187–191 (2014). https:// doi. org/ 10. 1016/j. fuproc. 2013. 09. 003
6. K.K. Tiwari, S.K. Basu, K.C. Bit, S. Banerjee, K.K. Mishra, Highconcentration
coal slurry from Indian coals using newly developed
additives. Fuel Process. Technol. 85 , 31–42 (2004). https:// doi.
org/ 10. 1016/ S0378- 3820(03) 00095-X
7. H. Dinçer, F. Boylu, A.A. Sirkeci, G. Ateşok, The eff ect of chemicals
on the viscosity and stability of coal water slurries. Int. J.
Miner. Process. 70 , 41–51 (2003). https:// doi. org/ 10. 1016/ S0301-
7516(02) 00149-7
8. R. Xu, W. Zhuang, Q. He, J. Cai, B. Hu, J. Shen, Eff ects of chemical
structure on the properties of carboxylate-type copolymer dispersant
for coal-water slurry. AIChE J. 55 , 2461–2467 (2009).
https:// doi. org/ 10. 1002/ aic. 11838
9. Z. Zhou, X. Li, J. Liang, J. Liu, J. Zhou, K. Cen, Surface coating
improves coal-water slurry formation of Shangwan coal. Energy
Fuels 25 , 3590–3597 (2011). https:// doi. org/ 10. 1021/ ef200 529h
10. P. Li, D. Yang, X. Qiu, W. Feng, Study on enhancing the slurry
performance of coal—water slurry prepared with low-rank coal.
J. Dispers. Sci. Technol. 36 , 1247–1256 (2015). https:// doi. org/
10. 1080/ 01932 691. 2014. 971367
11. B. Suleimenova, B. Aimbetov, D. Shah, E.J. Anthony, Y. Sarbassov,
Attrition of high ash Ekibastuz coal in a bench scale
fl uidized bed rig under O2/N2 and O2/CO2 environments. Fuel
Process. Technol. (2021). https:// doi. org/ 10. 1016/j. fuproc. 2021.
106775
12. N.E. and I.T.D. Organisation, CWM in Japan (1997)
13. M.S. Celik, G. Atesok, K. Seyhan, Preparation and combustion
of coal–water slurries, in Proceedings of coal Utilisation Conference,
Vitrin, Istanbul, Didim , pp. 137–157 (1993)
14. G.A. F. Boylu, Coal–water mixtures and their technologies: V, in
Coal Utilisation and Technology Symposium, Lebib Yalkın, Istanbul,
Ankara , pp. 195–212 (2000)
15. L. Li, C. Ma, S. Hu, M. He, H. Yu, Q. Wang, X. Cao, X. You,
Eff ect of the benzene ring of the dispersant on the rheological
characteristics of coal-water slurry: experiments and theoretical
calculations. Int. J. Min. Sci. Technol. 31 , 515–521 (2021). https://
doi. org/ 10. 1016/j. ijmst. 2021. 02. 001
16. H. Usur, Y. Sano, Thixotropy of highly loaded coal-water mixtures.
Nihon Reoroji Gakkaishi (J. Soc. Rheol. Japan). 14 , 123–
127 (1986). https:// doi. org/ 10. 1678/ rheol ogy19 73. 14.3_ 123
17. P.R. Tudor, D. Atkinson, R.J. Crawford, D.E. Mainwaring, The
eff ect of adsorbed and non-adsorbed additives on the stability of
coal-water suspensions. Fuel 75 , 443–452 (1996). https:// doi. org/
10. 1016/ 0016- 2361(95) 00267-7
18. M.O.T. Saeki, H. Usui, Eff ect of molecular structure of polysaccharide
on the stability of coal water mixtures. J. Chem. Eng. Jpn.
Jpn. 27 , 773–778 (1994)
19. Y.S.H. Usui, K. Machibara, Eff ect of stabilizing additives on
the stability of coal water mixtures. J. Chem. Eng. Jpn.Jpn. 20 ,
92–195 (1987)
20. R. Xu, Q. He, J. Cai, Y. Pan, J. Shen, B. Hu, Eff ects of chemicals
and blending petroleum coke on the properties of low-rank Indonesian
coal water mixtures. Fuel Process. Technol. 89 , 249–253
(2008). https:// doi. org/ 10. 1016/j. fuproc. 2007. 11. 026
21. H. Singh, S. Kumar, S.K. Mohapatra, S.B. Prasad, J. Singh, Slurryability
and fl owability of coal water slurry: eff ect of particle size
distribution. J. Clean. Prod. 323 , 129183 (2021). https:// doi. org/
10. 1016/j. jclep ro. 2021. 129183
22. J. Xiao, S. Wang, X. Duan, S. Ye, J. Wen, Z. Zhang, Rheological
models for temperature and concentration dependencies of coal
water slurry. Int. J. Coal Prep. Util. 00 , 1–19 (2019). https:// doi.
org/ 10. 1080/ 19392 699. 2019. 16967 80
23. P. Baruya, Losses in coal supply chain, IEA clean coal centre
(2012). https:// doi. org/ 10. 13140/ RG.2. 2. 19769. 26727
24. D. Gvozdyakov, A. Zenkov, Infl uence of petrochemicals on jet
characteristics after coal-water fuel spraying. Fuel Process. Technol.
218 , 106864 (2021). https:// doi. org/ 10. 1016/j. fuproc. 2021.
106864
25. V.I. Murko, V.A. Volkov, M.P. Baranova, M.V. Temlyantsev, V.V.
Chaplygin, Technology of waste coal processing used for fuel production.
IOP Conf. Ser. Earth Environ. Sci. 548 , 052055 (2020).
https:// doi. org/ 10. 1088/ 1755- 1315/ 548/5/ 052055
26. I.A. Korotkiy, E.N. Neverov, V.I. Murko, O.P. Chernikova, The
development of ecologically clean technology for coal use in
terms of the coal-water slurry usage. J. Phys. Conf. Ser. 1749 ,
012044 (2021). https:// doi. org/ 10. 1088/ 1742- 6596/ 1749/1/ 012044
27. M. Lewitt, Opportunities for fi ne coal, IEA Clean Coal Centre
(2011)
28. Y. Zhang, Z. Xu, Y. Tu, J. Wang, J. Li, Study on properties of coal
-sludge-slurry prepared by sludge from coal chemical industry.
Powder Technol. 366 , 552–559 (2020). https:// doi. org/ 10. 1016/j.
powtec. 2020. 03. 005
29. J Natoli, R. Mahar, B. Bobsein, Polycrylate thickeners for coal
water slurries: Slurry formation, stability and rheology, in International
Chemical Engineering Symposium Series , pp. 17–36
(1985)
30. H.S. Fogler, DOE/PC/80517-T1 (1986)
31. N. Sato, H. Ito, S. Tatsumi, Y. Kajibata, S. Takao, No Title, in
Proceedings of the 8th International Symposium on Coal Slurry
Fuels Preparation and Utilization , pp. 55–62 (1986)
32. R.W. Spark et al, No Title, in Fourth International Symposium on
Coal -Slurry Combustion, Pittsburgh Energy Technology Center,
Orlando, Florida (1982)
33. K. Furusawa, M. Ueda, M. Chen, N. Tobori, A new concept for
coal water mixture stabilization using a polyelectrolyte. Colloid
Polym. Sci. 273 , 490–495 (1995). https:// doi. org/ 10. 1007/ BF006
56894
34. D.F. Umar, H. Usui, Y. Komoda, Eff ect of dispersing and stabilizing
additives on rheological characteristics of the upgraded brown
coal water mixture. Fuel Process. Technol. 90 , 611–615 (2009).
https:// doi. org/ 10. 1016/j. fuproc. 2008. 12. 013
35. N. Ongsirimongkol, M.H. Narasingha, Eff ects of stabilizing agents
on stability and rheological characteristics of the highly-loaded
coal-water slurry. Int. J. Chem. Eng. Appl. 3 , 49–52 (2012).
https:// doi. org/ 10. 7763/ ijcea. 2012. v3. 158
36. S. Wang, J. Liu, S.V. Pisupati, D. Li, Z. Wang, J. Cheng, Dispersion
mechanism of coal water slurry prepared by mixing various
high-concentration organic waste liquids. Fuel 287 , 119340
(2021). https:// doi. org/ 10. 1016/j. fuel. 2020. 119340
37. D. Das, S.K. Das, P.K. Parhi, A.K. Dan, S. Mishra, P.K. Misra,
Green strategies in formulating, stabilizing and pipeline transportation
of coal water slurry in the framework of WATER-ENERGY
NEXUS: a state of the art review. Energy Nexus 4 , 100025 (2021).
https:// doi. org/ 10. 1016/j. nexus. 2021. 100025
38. D. Li, J. Liu, S. Wang, J. Cheng, Study on coal water slurries prepared
from coal chemical wastewater and their industrial application.
Appl. Energy 268 , 114976 (2020). https:// doi. org/ 10. 1016/j.
apene rgy. 2020. 114976
39. C. Auschra, E. Eckstein, A. Mühlebach, M.O. Zink, F. Rime,
Design of new pigment dispersants by controlled radical polymerization.
Prog. Org. Coat. 45 , 83–93 (2002). https:// doi. org/ 10.
1016/ S0300- 9440(02) 00048-6
40. M. Shafi ei, M. Balhoff , N.W. Hayman, Chemical and microstructural
controls on viscoplasticity in Carbopol hydrogel. Polymer
139 , 44–51 (2018). https:// doi. org/ 10. 1016/j. polym er. 2018. 01. 080
Publisher's Note Springer Nature remains neutral with regard to
jurisdictional claims in published maps and institutional affi liations.
Springer Nature or its licensor (e.g. a society or other partner) holds
exclusive rights to this article under a publishing agreement with the
author(s) or other rightsholder(s); author self-archiving of the accepted
manuscript version of this article is solely governed