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Received January 23, 2024
Accepted March 20, 2024
articles This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Highly Efficient Mg 0.75 Ce 0.25 Fe 12 O 19 @ZIF-67 Heterojunction Co-catalyst for Photo-reduction of Rhodamine B

Institute of Chemistry , The Islamia University of Bahawalpur 1Department of Chemistry, Center of Excellence for Innovation in Chemistry (PERCH-CIC), Center of Excellence in Materials Science and Technology, Faculty of Science , Chiang Mai University 2Institute for Advanced Study , Shenzhen University 3Department of Chemistry, College of Science , King Saud University 4Department of Chemistry, School of Natural Sciences , National University of Sciences and Technology ,
Korean Journal of Chemical Engineering, August 2024, 41(8), 2307-2319(13), https://doi.org/10.1007/s11814-024-00162-w

Abstract

This research presents a comprehensive investigation into the synthesis and application of novel composite photocatalysts,

namely Mg 0.75 Ce 0.25 Fe 12 O 19 @ZIF-67 for the degradation of Rhodamine B (RhB) dye under sunlight irradiation. The synthesis

involved the preparation of Mg 0.75 Ce 0.25 Fe 12 O 19 and ZIF-67 frameworks, followed by the fabrication of the composite

catalyst. Various characterization techniques, such as XRD, SEM, EDX, and FTIR, were employed to assess the structural,

morphological, and compositional properties of the synthesized materials. Photocatalytic experiments were conducted

to evaluate the effi ciency of the catalysts in degrading RhB, revealing remarkable enhancement in degradation effi ciency

(90%) using the composite photocatalyst compared to individual components. The eff ects of catalyst type, dosage, and pH

on the degradation process were systematically investigated. Furthermore, a proposed mechanism elucidated the role of the

Mg 0.75 Ce 0.25 Fe 12 O 19 @ZIF-67 cocatalyst for RhB degradation under solar light, highlighting the generation of radicals as

key contributors for degradation process.

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