Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
RATE MULTIPLICITY DUE TO INTERACTIONS BETWEEN ADSORBED SPECIES
Korean Journal of Chemical Engineering, January 1989, 6(1), 46-53(8), 10.1007/BF02698111
Download PDF
Abstract
A generalized Langmuir-Hinshelwood mechanism for the reaction A+1/2B2 ⇔ C has been studied. Lateral(nearest neighbor) interactions between the adsorbed species have been considered to analyze the multiple steady-states in the chemical reaction. Forward and reverse reaction rate constants have been evaluated via the lattice-gas model with the absolute rate theory. The simulation by the proposed model can predict multiple steady-states and hysteresis. Experimental correlation was made for the rate multiplicity observed by sung[3] on CO oxidation reaction.
