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EFFECT OF REACTION TEMPERATURE ON THE SELECTIVITY OF OXIDATIVE METHANE COUPLING OVER LEAD OXIDE
Korean Journal of Chemical Engineering, January 1989, 6(1), 54-55(2), 10.1007/BF02698112
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Abstract
In the oxidative coupling of methane over lead oxide, reaction temperature is a critical variable which determines the reaction pathway of methyl intermediates on the surface. Low temperature favors oxidation to carbon oxides, while high temperature favors desorption as methyl radicals.