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SELECTIVE CONVERSION OF NITROBENZENE TO PHENYLCARBAMATES CATALYZED BY Pd(II) AND HETEROPOLYACIDS
Korean Journal of Chemical Engineering, April 1990, 7(2), 145-147(3), 10.1007/BF02705060
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Abstract
A homogeneous catalyst system of Pd(II) and a heteropolyacid(HPA) converts nitrobenzene to N-phenylcarbamate with a selectivity of 96.3% at 100% nitrobenzene conversion, which appears to be the best value known in the literature. However, the catalyst forms solid deposits during the reaction.
References
Ozaki S, Chem. Rev., 72, 457 (1972)
U.S. Patent, 4,600,793 (1986)
U.S. Patent, 4,603,216 (1986)
Cenini S, Pizzotti M, Crotti C, Porta F, LaMonica G, J. Chem. Soc.-Chem. Commun., 1286 (1984)
Cenini S, Crotti C, Pizzotti M, Porta F, J. Org. Chem., 53, 1243 (1988)
Halligudi SB, Chaudhari RB, Doraiswamy LK, Ind. Eng. Chem. Process Des. Dev., 23, 794 (1984)
Gupte SB, Chaudhari RB, J. Mol. Catal., 34, 241 (1986)
Alessio E, Mestroni G, J. Org. Chem., 291, 117 (1985)
U.S. Patent, 4,178,455 (1979)
Fukuoka S, Chono M, Kohno M, J. Org. Chem., 49, 1458 (1984)
Mateev KI, Zhighina EG, Shitova NR, Kuznetsova LI, Kinet. Katal., 18, 380 (1977)
Nisono M, "Chemistry and Uses of Molybdenum," Climax, Ann Arbor, 289 (1982)
Golodov VA, Jumakaeva BS, J. Mol. Catal., 35, 309 (1986)
Japanese Kokai 56-138159 (1981)
Rocchiccioli-Deltcheff C, Thouvenot R, Franck R, Spectrochim. Acta, 32A, 587 (1976)
Fruchart JM, Herve G, Launay JP, Massart R, J. Inorg. Nucl. Chem., 38, 1627 (1976)
U.S. Patent, 4,600,793 (1986)
U.S. Patent, 4,603,216 (1986)
Cenini S, Pizzotti M, Crotti C, Porta F, LaMonica G, J. Chem. Soc.-Chem. Commun., 1286 (1984)
Cenini S, Crotti C, Pizzotti M, Porta F, J. Org. Chem., 53, 1243 (1988)
Halligudi SB, Chaudhari RB, Doraiswamy LK, Ind. Eng. Chem. Process Des. Dev., 23, 794 (1984)
Gupte SB, Chaudhari RB, J. Mol. Catal., 34, 241 (1986)
Alessio E, Mestroni G, J. Org. Chem., 291, 117 (1985)
U.S. Patent, 4,178,455 (1979)
Fukuoka S, Chono M, Kohno M, J. Org. Chem., 49, 1458 (1984)
Mateev KI, Zhighina EG, Shitova NR, Kuznetsova LI, Kinet. Katal., 18, 380 (1977)
Nisono M, "Chemistry and Uses of Molybdenum," Climax, Ann Arbor, 289 (1982)
Golodov VA, Jumakaeva BS, J. Mol. Catal., 35, 309 (1986)
Japanese Kokai 56-138159 (1981)
Rocchiccioli-Deltcheff C, Thouvenot R, Franck R, Spectrochim. Acta, 32A, 587 (1976)
Fruchart JM, Herve G, Launay JP, Massart R, J. Inorg. Nucl. Chem., 38, 1627 (1976)
