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RODIUM-CATALYZED CARBONYLATION OF METHYL GLYCOLATE AND GLYCOLIC ACID
Korean Journal of Chemical Engineering, January 1991, 8(1), 53-55(3), 10.1007/BF02697698
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Abstract
Catalytic carbonylation of methyl glycolate in the presence of a homogeneous Rh com-plex and an iodide promoter yields actoxy methyl acetate and acetic acid. Carbonylation of glycolic acid under the same conditions gives acetic acid and CO2, probably from decomposition of the maloinc acid intermediate.
References
Suzuki T, Matsuki T, Kudo K, Sugita N, Nippon Kagaku Kaishi, 1483 (1983)
Shinoda K, Yasuda K, Chem. Lett., 9 (1985)
Shinoda K, Yasuda K, Bull. Chem. Soc. Jpn., 58, 3082 (1985)
Gobolos S, Talas E, Margitfalvi J, "Heterogeneous Catalysis and Fine Chemicals," M. Guisnet et al. eds., Elsevier, Amsterdam, p. 337 (1988)
Hiratani T, Noziri S, Chem. Econ. Eng. Rev., 17, 21 (1985)
Ikarashi T, Chem. Econ. Eng. Rev., 12, 31 (1980)
Mullen A, "New Synthesis with Carbon Monoxide," J. Falbe, ed., Springer-Verlag, Berlin, p. 243 (1980)
Lapporte SJ, Kurkov VP, "Organotransition Metal Chemistry: Proceedings of the First Japanese-American Seminar on Prospects in Organo-transition Metal Chemistry," Y. Ishii and M. Tsutsui, M. eds., Plenum, New York, p. 199 (1975)
Grayson M, Kirk-Othmer Encyclopedia of Chemical Technology, 3th Ed.," Vol. 14, Wiley, New York, p. 794 (1980)
Shinoda K, Yasuda K, Chem. Lett., 9 (1985)
Shinoda K, Yasuda K, Bull. Chem. Soc. Jpn., 58, 3082 (1985)
Gobolos S, Talas E, Margitfalvi J, "Heterogeneous Catalysis and Fine Chemicals," M. Guisnet et al. eds., Elsevier, Amsterdam, p. 337 (1988)
Hiratani T, Noziri S, Chem. Econ. Eng. Rev., 17, 21 (1985)
Ikarashi T, Chem. Econ. Eng. Rev., 12, 31 (1980)
Mullen A, "New Synthesis with Carbon Monoxide," J. Falbe, ed., Springer-Verlag, Berlin, p. 243 (1980)
Lapporte SJ, Kurkov VP, "Organotransition Metal Chemistry: Proceedings of the First Japanese-American Seminar on Prospects in Organo-transition Metal Chemistry," Y. Ishii and M. Tsutsui, M. eds., Plenum, New York, p. 199 (1975)
Grayson M, Kirk-Othmer Encyclopedia of Chemical Technology, 3th Ed.," Vol. 14, Wiley, New York, p. 794 (1980)
