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CORRELATION OF PITZER ION INTERACTION PARAMETERS
Korean Journal of Chemical Engineering, April 1991, 8(2), 105-113(9), 10.1007/BF02697384
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Abstract
A new correlation predicting the activity coefficients of aqueous electrolyte solutions between Pitzer ion interaction parameters and ionic properties (ionic charge, radius and entropy)is developed. The substances include uni-uni and uni-bi type of single salts for which data are available. The results of correlation show linear relations for uni-uni type, and quadratic equations for uni-bi type. Many of the trends in the calculated activity coefficients for electrolyte solutions can be correlated with respect to the effect of the ions on the structure of the water and explained by structure-making and -breaking concept. these kinds of correlation amy be useful in predicting values for salts that have no measurement of the activity coefficients.
References
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Pitzer KS, Mayorga G, J. Sol. Chem., 3, 539 (1974)
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Hamer WJ, Wu YC, J. Phys. Chem. Ref. Data., 1, 1047 (1972)
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Peleg M, J. Phys. Chem., 76, 1019 (1972)
Lemley ATG, Plane RA, J. Chem. Phys., 57, 1648 (1972)
Pitzer KS, Mayorga G, J. Phys. Chem., 77, 2300 (1973)
Pitzer KS, Mayorga G, J. Sol. Chem., 3, 539 (1974)
Pitzer KS, Kim JJ, J. Am. Chem. Soc., 96, 5701 (1974)
Kim HT, Frederick WJ, J. Chem. Eng. Data, 33, 177 (1988)
Kim HT, Frederick WJ, J. Chem. Eng. Data, 33, 278 (1988)
Harvie CE, Weare JH, Geochim. Cosmochim. Acta, 44, 981 (1980)
Harvie CE, Eugster HP, Weare JH, Geochim. Cosmochim. Acta, 46, 1603 (1982)
Harvie CE, Moller N, Weare JH, Geochim. Cosmochim. Acta, 48, 723 (1984)
Kelly B, Frederick WJ, AIChE Forest Products Division, Seattle (1986)
Chen CC, Britt HI, Boston JF, Evans LB, AIChE J., 25, 820 (1979)
Whitfield M, Mar. Chem., 3, 197 (1975)
Whitfield M, Geochim. Cosmochim. Acta, 39, 1545 (1975)
Bernal JD, Fowler RH, J. Chem. Phys., 1, 515 (1933)
Blandamer MJ, Chem. Soc. London Quart. Rev., 24, 169 (1970)
Huheey JE, Inorganic Chemistry; Principles of Structure and Reactivity, 2nd ed., New York, Harper & Row, p. 889 (1978)
Cartledge GH, J. Am. Chem. Soc., 50, 2855 (1928)
Cartledge GH, J. Am. Chem. Soc., 50, 2863 (1928)
Wood SA, Crerar DA, Brantley SL, Borcsik M, Am. J. Sci., 284, 668 (1984)
Buetier D, Renon H, Ind. Eng. Chem. Process Des. Dev., 17(3), 220 (1978)
Criss CM, Cobble JW, J. Am. Chem. Soc., 86, 5385 (1964)
Pitzer KS, Theory: Ion Interaction Approach, in Activity Coefficients in Electrolyte Solutions, Vol. 1, Pytkowicz, R.M., Editor CRC Press, Inc., Boca Raton, FL (1979)
Staple BR, Personal Communication (1986)
Staple BR, Ninth Intl. Assn. for Properties of Steam Conf. Moscow, Sept. (1984)
Glushko VP, Thermodynamic Constants of Mater, Vol. 1-10, Academy of Sci. of the U.S.S.R., Moscow (1965)
Wagman DD, Evans WH, Parker VB, Schumm RM, Halow I, Bailey SM, Churney KL, Nutall RL, J. Phys. Chem. Ref. Data., 11(2) (1982)
Morris DFC, Structure Bonding, 4, 63 (1968)
Marcus Y, J. Sol. Chem., 12, 271 (1983)
Pauling L, Nature of the Chemical Bond. Cornell Univ. Press, Ithaca (1960)
Hamer WJ, Wu YC, J. Phys. Chem. Ref. Data., 1, 1047 (1972)
Wu YC, Harner WJ, J. Phys. Chem. Ref. Data, 9, 513 (1980)
Roy RN, Gibbons JJ, Bliss DP, Casebolt RG, Baker BK, J. Sol. Chem., 9, 911 (1980)
Peleg M, J. Phys. Chem., 76, 1019 (1972)
Lemley ATG, Plane RA, J. Chem. Phys., 57, 1648 (1972)
