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- In relation to this article, we declare that there is no conflict of interest.
- Publication history
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Received August 23, 2023
Accepted August 23, 2023
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
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Room Temperature Ionic Liquids as Replacements for Conventional Solvents - A Review
Department of Chemical and Process Engineering, University of Canterbury, New Zealand, Korea 1Cosmologic, Leverkusen, D-51381, Germany
Korean Journal of Chemical Engineering, May 2002, 19(3), 357-362(6), 10.1007/BF02697140
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Abstract
Room temperature ionic liquids are salts that are liquids at ambient temperature. They are excellent solvents for a broad range of polar organic compounds and they show partial miscibility with aromatic hydrocarbons. Typical room temperature ionic liquids have a stable liquid range of over 300 K and have a very low vapor pressure at room temperature. Ionic liquids that are not hydrolyzed show a wide range of solubility in water. These unique properties have suggested that they might be useful as environmentally benign solvents that could replace volatile organic_x000D_
compounds (VOC). By varying the length and branching of the alkane chains of the cationic core and the anionic precursor, the solvent properties of ionic liquids should be able to be tailored to meet the requirements of specific applications to create an almost infinitely set of “designer solvents”. A review of recent applications of ionic liquids is presented along with some results of measurements of liquid-liquid equilibria and partition coefficients with alcohols. The results are compared with predictions based on quantum mechanic calculations.
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Chauvin Y, Mussmann L, Olivier H, Angew. Chem.-Int. Edit., 34, 2698 (1995)
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Fannin AA, Floreani DA, King LA, Landers JS, Piersma BJ, Stech DJ, Vaughn RL, Wilkes JS, Williams JL, J. Phys. Chem., 88, 2614 (1984)
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Huddleston JG, Willauer HD, Swatloski RP, Visser AE, Rogers RD, Chem. Commun., 1765 (1998)
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Klamt A, Eckert F, Fluid Phase Equilib., 172(1), 43 (2000)
Koel M, Proc. Est. Acad. Sci. Chem., 49, 145 (2000)
Kaufmann DE, Nouroozian M, Henze H, Synlett, 1091 (1996)
Liao Q, Hussey CL, J. Chem. Eng. Data, 41(5), 1126 (1996)
Muller La, DuPont J, De Souza RF, Macromol. Rapid Commun., 19, 409 (1998)
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