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- In relation to this article, we declare that there is no conflict of interest.
- Publication history
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Received July 11, 2018
Accepted August 16, 2018
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
Most Cited
Decrease in hydrogen crossover through membrane of polymer electrolyte membrane fuel cells at the initial stages of an acceleration stress test
Department of Chemical Engineering, Sunchon National University, 315 Maegok-dong, Suncheon, Jeonnam 57922, Korea 1Kolong Research Institute, 207-2 Mabuk-dong, Giheung-gu, Youngin-si, Gyunggi-do 16910, Korea
parkkp@sunchon.ac.kr
Korean Journal of Chemical Engineering, November 2018, 35(11), 2290-2295(6), 10.1007/s11814-018-0142-5
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Abstract
An acceleration stress test (AST) was performed to evaluate the durability of a polymer membrane in a polymer electrolyte membrane fuel cell (PEMFC) for 500 hours. Previous studies have shown that hydrogen crossover measured by linear sweep voltammetry (LSV) increases when the polymer membrane deteriorates in the AST process. On the other hand, hydrogen crossover of the membrane often decreases in the early stages of the AST test. To investigate the cause of this phenomenon, we analyzed the MEA operated for 50 hours using the AST method (OCV, RH 30% and 90 °C). Cyclic voltammetry and transmission electron showed that the electrochemical surface area (ECSA) decreased due to the growth of electrode catalyst particles and that the hydrogen crossover current density measured by LSV could be reduced. Fourier transform infrared spectroscopy and thermogravimetric/differential thermal analysis showed that -S-O-S- crosslinking occurred in the polymer after the 50 hour AST. Gas chromatography showed that the hydrogen permeability was decreased by -S-O-S- crosslinking. The reduction of the hydrogen crossover current density measured by LSV in the early stages of AST could be caused by both reduction of the electrochemical surface area of the electrode catalyst and -S-O-S- crosslinking.
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References
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Qiao JL, Saito M, Hayamizu K, Okada T, J. Electrochem. Soc., 153(6), A967 (2006)
Endoh E, Terazono S, Widjaja H, Takimoto Y, Electrochem. Solid State Lett., 7(7), A209 (2004)
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Liang Z, Chen W, Liu J, Wang S, Zhou Z, Li W, Sun G, Xin Q, J. Membr. Sci., 23, 39 (2004)
Ludvigsson M, Lindgren J, Tegenfeldt J, Electrochim. Acta, 45(14), 2267 (2000)
Cons FD, ECS Trans., 16(2), 235 (2008)
Danilczuk M, Coms FD, Schlick S, J. Phys. Chem. B, 113(23), 8031 (2009)
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Ohguri N, Nosaka AY, Nosaka Y, J. Power Sources, 195(15), 4647 (2010)
Liu W, Zuckerbrod D, J. Electrochem. Soc., 152(6), A1165 (2005)
Kundu S, Fowler MW, Simon LC, Abouatallah R, Beydokhti N, J. Power Sources, 183(2), 619 (2008)
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Deng Q, Moore RB, Mauritz KA, J. Appl. Polym. Sci., 68(5), 747 (1998)
