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Bio-mediated Synthesis of ZnS–ZnO Nanocomposite from Cucumis melo Pulp and Chicken Feathers: Photodegradation of Dyes and Antibacterial Activities

Centre for Nanomaterials, Department of Chemistry , Bangalore University , Sneha Bhavana, Jnana Bharathi Campus , Bengaluru , Karnataka 560056 , India 1Department of Chemistry , B. M. S. College of Engineering , Bengaluru 560019 , India
sowbhagyachem@gmail.com
Korean Journal of Chemical Engineering, February 2024, 41(2), 515-531(17), https://doi.org/10.1007/s11814-024-00058-9

Abstract

An innovative way was found for the synthesis of effi cient photocatalyst in the form of ZnS–ZnO nanocomposite from

Cucumis melo pulp and chicken feather powder as a source of fuel and oxygen and sulfur, respectively, by combustion

followed by hydrothermal method and is reported in this work. Diff erent analytical techniques are employed, such as

XRD, SEM, TEM, PL EDS, FT-IR, DRS, and EIS techniques for structural, morphological, optical, and electrochemical

properties. The SEM analysis confi rmed ZnS–ZnO nanocomposite formation. The XRD data of ZnS–ZnO nanocomposite

resembled pure crystalline ZnO and ZnS nanoparticles. DRS confi rmed the band gap of the synthesized material, which

was calculated using a K-M plot and found to be 3.29 eV, 3.38 eV, and 3.12 eV for ZnO, ZnS nanoparticles, and ZnS-ZnO

nanocomposite, respectively. The synthesized ZnS–ZnO nanocomposite showed enhanced photocatalytic activity towards

MB [92%], RhB [98.4%], and CR [90.9%] dyes in water under UV light source. Radicals formation was confi rmed by the

ESR technique. TOC analysis was done to verify the degradation of dyes. ZnS–ZnO nanocomposite also exhibited potent

or robust antibacterial activity.

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