ISSN: 0256-1115 (print version) ISSN: 1975-7220 (electronic version)
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In relation to this article, we declare that there is no conflict of interest.
Publication history
Received July 12, 2023
Accepted August 13, 2023
articles This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Most Cited

Industrial Solid Waste-Based Layered Double Hydroxide Composite with Enhanced Adsorption Affi nity to Congo Red, Acid Red, and Reactive Red

College of Biological Chemical Science and Engineering , Jiaxing University 1Education and Research Center for Smart Energy and Materials , Inha University
seshim@inha.ac.kr
Korean Journal of Chemical Engineering, March 2024, 41(3), 829-838(10), https://doi.org/10.1007/s11814-024-00088-3

Abstract

The synthesis of hierarchically porous materials from industrial solid waste as catalysts or adsorbents has attracted much

attention in environmental pollution control. The present work highlights the synthesis of a series of MgFeAl layered double

hydroxide (LDH) with diff erent ratios of Mg/(Fe + Al) from red mud and ferronickel slag under diff erent pH to decolorize

three red dye solutions, namely, Congo red (CR), acid red (AR), and reactive red (RR). The maximum adsorption capacity

(386.1 mg.g −1 ) for CR was obtained by the MgFeAl-LDH sample with Mg/(Fe + Al) mole ratio of 2 synthesized under pH

10. The optimized synthesis parameters led to a high surface area and large pore volume of MgFeAl-LDH, thereby enhancing

the mass transfer of adsorbate to the active sites of the adsorbent. Further, the MgFeAl-LDH sample was also effi cient

in removing AR (120.9 mg.g −1 ) and RR (114 mg.g −1 ). Moreover, the adsorption kinetics and isotherms of MgFeAl-LDH

fi tted well with the pseudo-second-order and Langmuir models, respectively. The MgFeAl-LDH system developed a valuable

approach to utilize industrial waste for dye removal.

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