ISSN: 0256-1115 (print version) ISSN: 1975-7220 (electronic version)
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In relation to this article, we declare that there is no conflict of interest.
Publication history
Received November 25, 2023
Accepted March 28, 2024
articles This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Most Cited

Theoretically and Experimentally Exploring the Inhibition Eff ect of Imidazole Sulfonic Acid Derivatives with Multiple Adsorption Sites in 1.0 mol/L HCl

State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation , Southwest Petroleum University 1School of New Energy and Materials , Southwest Petroleum University 2School of Petroleum Engineering , Yangtze University 3College of Material and Chemical Engineering , Tongren University
Yhlin28@163.com
Korean Journal of Chemical Engineering, June 2024, 41(7), 2117-2132(16), https://doi.org/10.1007/s11814-024-00166-6

Abstract

Corrosion inhibitors have played a huge role in daily life and industrial production. Imidazole and sulfonic acid groups have

high corrosion inhibition capabilities. To further improve their excellent corrosion inhibition performance, two new sulfonic

acid azole corrosion inhibitors (YM and ZM) were synthesized and the eff ect of carbon chain length on the imidazole sulfonic

acid corrosion inhibitor was studied. The weight loss and electrochemical results indicated that the corrosion inhibition

effi ciency signifi cantly increased with the increase of YM and ZM concentration. At 1.0 g/L of ZM, the corrosion inhibition

effi ciency of weight loss, EIS and Tafel were 95.02%, 86.61%, and 98.49%, respectively. Electrochemistry further indicated

that ZM and YM could form a stable protective fi lm on the surface of Q235 and increased the charge transfer resistance,

thereby improving their corrosion inhibition effi ciency and belong to cathodic corrosion inhibitors. SEM–EDS, FT-IR, and

XPS confi rmed that YM and ZM could eff ectively adsorb on the surface of Q235, and further demonstrated theories through

density functional theory and molecular dynamics simulation.

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