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In relation to this article, we declare that there is no conflict of interest.
Publication history
Received November 28, 2023
Accepted January 13, 2024
articles This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Changes in Physical Properties with Varying Impregnation Temperatures and Compression Times During Fabrication of Carbon Blocks Using Needle Cokes and Pitch

School of Materials Science and Engineering , Kumoh National Institute of Technology
Korean Journal of Chemical Engineering, June 2024, 41(7), 2153-2161(9), https://doi.org/10.1007/s11814-024-00121-5

Abstract

Impregnation was conducted to decrease the pores formed during the carbonization process after manufacturing carbon blocks

using needle cokes and coal tar pitch. This was carried out in the order of heating, subjecting to vacuum, and compression, and

changes in mechanical and electrical properties before and after impregnation were analyzed with impregnation temperature

and compression time as variables. The impregnation temperatures were 150, 200, and 250 °C, and compression times were

30, 60, and 90 min. The optimal impregnation temperature was 200 °C, resulting in a 12.5% increase in bulk density and a

26.0% decrease in porosity after impregnation of the carbon blocks. The optimal compression time was 60 min, leading to a

14.3% increase in bulk density and a 24.0% decrease in porosity after impregnation. Under the selected optimal conditions,

after three impregnation cycles, the bulk density increased by 33.8% compared to the initial state (0 cycles 1.259 g/cm 3 → 3

cycles 1.685 g/cm 3 ), and porosity decreased by 56.8% (0 cycles 39.1% → 3 cycles 16.9%). According to the performance

evaluation of carbon blocks, electrical resistivity decreased by 52.0% (72.5 μΩm → 34.8 μΩm) and fl exural strength increased

by 368.3% (6.0 MPa → 28.1 MPa). The substantial increase in fl exural strength was attributed to the reduction in porosity.

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