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In relation to this article, we declare that there is no conflict of interest.
Publication history
Received February 7, 2024
Accepted May 1, 2024
articles This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Most Cited

Change of Mechanical Properties of e-PTFE Support by Electrochemical Degradation in Polymer Electrolyte Membrane Fuel Cell

Department of Chemical Engineering , Sunchon National University 1SANG-A FRONTEC CO.
parkkp@scnu.ac.kr
Korean Journal of Chemical Engineering, August 2024, 41(8), 2433-2440(8), https://doi.org/10.1007/s11814-024-00182-6

Abstract

In polymer electrolyte membrane fuel cell (PEMFC), the cost and durability are main challenges to commercialization. To

achieve the long-term durability target, the durability of PEMFC materials should be further improved. In this paper, we

investigated the chemical and electrochemical degradation of the expanded polytetrafl uoroethylene (e-PTFE) support and

examined how it infl uences the mechanical properties of the e-PTFE support. We conducted the Fenton test and open circuit

voltage (OCV) holding and analyzed the chemical and physical structural changes of the e-PTFE support by utilizing Fourier

transform infrared spectroscopy (FT-IR), scanning electron microscope (SEM), and tensile test. After the chemical

and electrochemical degradations, the molecular bonds of e-PTFE were broken, and the microstructures of e-PTFE were

deformed. As the result the mechanical properties of e-PTFE showed signifi cant decrease. Consequently, our results show

that the e-PTFE support is deteriorated chemically during PEMFC operation, and this chemical degradation lead reduction

of mechanical strength.

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