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- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
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Received February 23, 2023
Revised March 28, 2023
Accepted March 31, 2023
- Acknowledgements
- This paper was supported by Konkuk University Premier Research Fund in 2020
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Effects of adsorbent sampling variables on the accurate measurement of isoprene
In-Young Choi1
Trieu-Vuong Dinh1
Ki-Joon Kim1
Dong-Eun Kim2
Bong-Hyun Jun2
Seungae Lee3
Young-Min Park4
Jo-Chun Kim1†
1Department of Civil and Environmental Engineering, Konkuk University, 120 Neungdong-ro, Gwangjin-gu, Seoul 05029, Korea 2Department of Bioscience and Biotechnology, Konkuk University, 120 Neungdong-ro, Gwangjin-gu, Seoul 05029, Korea 3Department of Chemical Engineering, Konkuk University, 120 Neungdong-ro, Gwangjin-gu, Seoul 05029, Korea 4Department of Immunology, KU Open Innovation Center, School of Medicine, Konkuk University, Chungju 27376, Korea
jckim@konkuk.ac.kr
Korean Journal of Chemical Engineering, December 2023, 40(12), 2886-2891(6), 10.1007/s11814-023-1460-9
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Abstract
Isoprene is an important volatile organic compound causing photochemical smog in the atmosphere; thus,
accurate analysis of isoprene is essential. In this study, the effect of sampling conditions, including adsorbent types,
sampling temperatures, and flow rates on the recovery of isoprene, was investigated. Common adsorption traps of isoprene, including Tenax TA/Carbosieve SIII, Tenax TA/Carbotrap, were used as adsorbents. Sampling temperatures varied from 25 o
C to 40 o
C. Sampling flow rates were 50, 100, and 200 mL min1
. It was found that the Tenax/Carbotrap
trap revealed the highest isoprene recovery rate; however, the Tenax/Carbosieve SIII trap depicted more significant loss
of isoprene than the other one. As for sampling variables, the lower the temperatures and flow rates concerned were,
the higher the isoprene recovery was. It was concluded that sampling temperatures and flow rates should be 35 o
C
and 50 mL min1
during a sampling process, respectively. In addition, Carbosieve SIII should not be used for isoprene sampling due to its poor recovery rate
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4. J. Kim, J. E. Lee, H. W. Lee, J. K. Jeon, J. H. Song, S. C. Jung, Y. F.Tsang and Y. K. Park, J. Hazard. Mater., 397, 122577 (2020).
5. P. A. Dominutti, J. R. Hopkins, M. Shaw, G. P. Mills, H. A. Le, D. H.Huy, G. L. Forster, S. Keita, T. T. Hien and D. E. Oram, Environ.Pollut., 318, 120927 (2023).
6. G. A. Novak and T. H. Bertram, Acc. Chem. Res., 53, 1014 (2020).
7. K. Na, Y. P. Kim, I. Moon and K. C. Moon, Chemosphere, 55, 585 (2004).
8. Q. Liang, X. Bao, Q. Sun, Q. Zhang, X. Zou, C. Huang, C. Shen and Y. Chu, Environ. Pollut., 265, 114628 (2020).
9. A. Kiendler-Scharr, J. Wildt, M. D. Maso, T. Hohaus, E. Kleist, T. F. Mentel, R. Tillmann, R. Uerlings, U. Schurr and A. Wahner, Nature,461, 381 (2009).
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24. J. V. Eijk and D. Kotzias, Fresenius Environ. Bull., 3, 220 (1994).
25. H. F. Linskens and J. F. Jackson, Modern Methods of Plant Analysis Volume 13: Plant Toxin Analysis, Springer-Verlag, Berlin (1992).
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28. J.-H. Kim, H. E. Lee and S. J. Yoon, Atmosphere, 14, 485 (2023).
29. M. Even, E. Juritsch and M. Richter, Anal. Chim. Acta, 1238, 340561 (2023).
30. S. W. Harshman, A. E. Jung, K. E. Strayer, B. L. Alfred, J. Mattamana, A. R. Veigl, A. I. Dash, C. E. Salter, M. A. Stoner-Dixon, J. T. Kelly, C. N. Davidson, R. L. Pitsch and J. A. Martin, J. Breath Res., 17, 027101 (2023).
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32. A. Guion, S. Turquety, A. Cholakian, J. Polcher, A. Ehret and J. Lathiere, Atmos. Chem. Phys., 23, 1043 (2023).
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35. P. V. Doskey and W. Gao, J. Geophys. Res., 104, 21263 (1999).
36. W. J. Broadgate, P. S. Liss and S. A. Penkett, Geophys. Res. Lett., 24, 2675 (1997).
37. Y.-H. Kim and K.-H. Kim, Anal. Chem., 85, 7818 (2013).
38. D. Helmig and L. Vierling, Anal. Chem., 67, 4380 (1995).
39. Y.-H. Kim, K.-H. Kim, J. E. Szulejko and D. Parker, Anal. Chem., 86, 6640 (2014).
40. F. Innocenti, R. A. Robinson, T. D. Gardiner and A. J. Finalyson, Differential Absorption Lidar (DIAL) Quantification of VOC Fugitive Emissions from Small Sources in Los Angeles Area, USA, OCTOBER 2015, National Physical Laboratory, Middlesex, (2017).
41. O. Monje, J. Catechis and J. C. Sager, SAE Tech. Pap., 2007-01-3249 (2007).
42. V. Camel and M. Caude, J. Chromatogr. A, 710, 3 (1995).
43. A. Poormohammadi, A. Bahrami, A. Ghiasvand, F. G. Shahna and M. Farhadian, J. Environ. Health Sci. Eng., 17, 1045 (2019).
44. P. Foley, N. Gonzalez-Flesca, I. Zdanevitch and J. Corish, Environ.Sci. Technol., 35, 1671 (2001).
45. J.-H. Ahn, K.-H. Kim, J. E. Szulejko, E. E. Kwon and A. Deep, Microchem. J., 125, 142 (2016).
46. Ö. O. Kuntasal, D. Karman, D. Wang, S. G. Tuncel and G. Tuncel,J. Chromatogr. A, 1099, 43 (2005).
47. M. Richter, E. Juritsch and O. Jann, J. Chromatogr. A, 1626, 461389 (2020).
48. C. Geron, A. Guenther, J. Greenberg, H. W. Loescher, D. Clark and B. Baker, Atmos. Environ., 36, 3793 (2002).
49. B. Tolnai, J. Hlavay, D. Möller, H.-J. Prümke, H. Becker and M.Dostler, Microchem. J., 67, 163 (2000).
50. G. Barrefors and G. Petersson, Chemosphere, 30, 1551 (1995).
51. G. Barrefors and G. Petersson, J. Chromatogr. A, 643, 71 (1993).
52. K. Dettmer, T. Knobloch and W. Engewald, Fresenius J. Anal. Chem.,366, 70 (2000)
