Korean Journal of Chemical Engineering, Vol.33, No.11, 3128-3133, 2016
Thermogravimetric characteristics of α-cellulose and decomposition kinetics in a micro-tubing reactor
The pyrolysis characteristics and kinetics of α-cellulose were investigated using thermogravimetric analyzer (TGA) and micro tubing reactor, respectively. Most of the α-cellulose decomposed between 250 and 400 ℃ at heating rate of 5-20 ℃/min. The apparent activation energy was observed in the range of 263.02 kJ mol-1 to 306.21 kJ mol-1 at the conversion of 10-80%. The kinetic parameters were determined by nonlinear least-squares regression of the experimental data, assuming first-order kinetics. It was found from the kinetic rate constants that the predominant reaction pathway was A(α-cellulose) to B(bio-oil) rather than A(α-cellulose) to C(gas; C1-C4) and/or to B(bio-oil) to C(gas; C1-C4) at temperatures of 340-360 ℃.
[References]
Jefferson M, Renew. Energy , 31 (5), 571, 2006
Nigam PS, Singh A, Prog. Energy Combust. Sci. , 37 (1), 52, 2011
Park SH, Cho HJ, Ryu C, Park YK, J. Ind. Eng. Chem. , 36 , 314, 2016
Demirba A, Fuel , 80 , 1885, 2001
Manya JJ, Velo E, Puigjaner L, Ind. Eng. Chem. Res. , 42 (3), 434, 2003
Parthasarathy P, Narayanan S, Korean J. Chem. Eng. , 32 (11), 2236, 2015
Rao TR, Sharma A, Energy , 23 (11), 973, 1998
Raveendran K, Ganesh A, Khilar KC, Fuel , 75 , 987, 1996
Yang HP, Yan R, Chen HP, Lee DH, Zheng CG, Fuel , 86 (12-13), 1781, 2007
Zhu G, Zhu X, Xiao Z, Yi F, J. Anal. Appl. Pyrolysis , 94 , 126, 2012
Deguchi S, Tsujii K, Horikoshi K, Chem. Commun. , 31 , 3293, 2006
Kim SH, Lee CM, Kafle K, Korean J. Chem. Eng. , 30 (12), 2127, 2013
Wang S, Du Y, Zhang W, Cheng X, Wang J, Korean J. Chem. Eng. , 31 (10), 1786, 2014
Patwardhan PR, Satrio JA, Brown RC, Shanks BH, J. Anal. Appl. Pyrolysis , 86 , 323, 2009
Antal MJ, Varhegyi G, Jakab E, Ind. Eng. Chem. Res. , 37 (4), 1267, 1998
Antal MJ, Varhegyi G, Ind. Eng. Chem. Res. , 34 (3), 703, 1995
Varhegyi G, Jakab E, Antal MJ, Energy Fuels , 8 (6), 1345, 1994
Bradbury AG, Sakai Y, Shafizadeh F, J. Anal. Appl. Pyrolysis , 23 , 3271, 1979
Agrawal RK, Can. J. Chem. Eng. , 66 , 413, 1988
Di Blasi C, Prog. Energy Combust. Sci. , 34 (1), 47, 2008
Chayaporn S, Sungsuk P, Sunphorka S, Kuchonthara P, Piumsomboon P, Chalermsinsuwan B, Korean J. Chem. Eng. , 32 (6), 1081, 2015
Kim SS, Kim J, Park YH, Park YK, Bioresour. Technol. , 101 (24), 9797, 2010
Kim SS, Kim SH, Fuel , 79 , 1943, 2000
Park YH, Kim J, Kim SS, Park YK, Bioresour. Technol. , 100 (1), 400, 2009
Othman MR, Park YH, Ngo TA, Kim SS, Kim J, Lee KS, Korean J. Chem. Eng. , 27 (1), 163, 2010
Choi GH, Kim SS, Kim J, Joo DS, Lee J, Appl. Chem. Eng. , 22 (5), 508, 2011
Ouajai S, Shanks R, Polym. Degrad. Stabil. , 89 , 327, 2005
Caballero J, Conesa J, Font R, Marcilla A, J. Anal. Appl. Pyrolysis , 42 , 159, 1997
Kim SS, Agblevor FA, Waste Manage. , 27 , 135, 2007
Maiti S, Purakayastha S, Ghosh B, Fuel , 86 (10-11), 1513, 2007
Soysa R, Choi YS, Choi SK, Kim SJ, Han SY, Korean J. Chem. Eng. , 33 (2), 603, 2016
Vamvuka D, Kakaras E, Kastanaki E, Grammelis P, Fuel , 82 (15-17), 1949, 2003
Wang G, Li W, Li BQ, Chen HK, Fuel , 87 (4-5), 552, 2008
Park HJ, Park YK, Dong JI, Kim JS, Jeon JK, Kim SS, Kim J, Song B, Park J, Lee KJ, Fuel Process. Technol. , 90 (2), 186, 2009
Lee EH, Park R, Kim H, Park SH, Jung SC, Jeon JK, Kim SC, Park YK, J. Ind. Eng. Chem. , In Press, 2016
Le TA, Ly HV, Kim J, Kim SS, Choi JH, Woo HC, Othman MR, Chem. Eng. J. , 250 , 157, 2014
Ko JH, Park RS, Jeon JK, Kim DH, Jung SC, Kim SC, Park YK, J. Ind. Eng. Chem. , 32 , 109, 2015
Ross AB, Jones JM, Kubacki ML, Bridgeman T, Bioresour. Technol. , 99 (14), 6494, 2008
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Choi JH, Kim SS, Woo HC, Journal of Industrial and Engineering Chemistry , 51 , 206, 2017
Lee YJ, Shafaghat H, Kim JK, Jeon JK, Jung SC, Lee IG, Park YK, Korean Journal of Chemical Engineering , 34 (8), 2180, 2017
Shafaghat H, Rezaei PS, Ro DH, Jae JH, Kim BS, Jung SC, Sung BH, Park YK, Journal of Industrial and Engineering Chemistry , 54 , 447, 2017
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