Korean Journal of Chemical Engineering, Vol.36, No.7, 1057-1068, 2019
Graphene/ternary layered double hydroxide composites: Efficient removal of anionic dye from aqueous phase
Ternary layered double hydroxide, MgCoAl (MCA) and its graphene-based composite (G/MCA) were fabricated via a simple co-precipitation technique. The composites along with their calcined products (MCA-C) and (G/ MCA-C) were used as adsorbents for the removal of an anionic dye, methyl orange (MO), from aqueous phase. The characterization results (scanning electron microscopy and transmission electron microscopy) revealed homogeneous dispersion of graphene onto the MCA. Calcination of G/MCA resulted in a rough and heterogeneous surface with significant improvement in oxygen functionalities and surface area, which plays a crucial role in improved dye adsorption performance. Adsorptive equilibrium was established at 240 min for MCA and G/MCA and 180min for MCA-C and G/MCA-C respectively at pH 3 and optimum dosage of 10mg. The Redlich-Peterson and Langmuir isotherm models closely describe the adsorption process with maximum adsorption capacities of 357.14, 384.62, 400.12 and 434.78mg/g for MCA, G/MCA, MCA-C, and G/MCA-C respectively. Kinetics modeling indicates the adequacy and fitness of the pseudo-second-order model. A thermodynamics evaluation substantiates the exothermic nature of the adsorption processes. The MO-graphene ternary LDH composite adsorption process is controlled by several mechanisms including hydrogen bonding, surface adsorption, chemical and electrostatic interactions with surface reconstruction. The high removal efficiency of the MO coupled with high recovery and reusability of these nanomaterials showcases their potential for deployment in wastewater treatment.
[References]
Blaisi NI, Zubair M, Ihsanullah S, Ali S, Kazeem TS, Manzar MS, Al-Kutti W, Al Harthi MA, Environ. Sci. Pollut. Res. , 25 , 34319, 2018
Sejie FP, Nadiye-Tabbiruka MS, Phys. Chem. , 6 , 39, 2016
Zubair M, Jarrah N, Ihsanullah, Khalid A, Manzar MS, Kazeem TS, Al-Harthi MA, J. Mol. Liq. , 249 , 254, 2018
Harrelkas F, Azizi A, Yaacoubi A, Benhammou A, Pons MN, Desalination , 235 (1-3), 330, 2009
Bulut E, Ozacar M, Sengil IA, J. Hazard. Mater. , 154 (1-3), 613, 2008
Uygur A, Coloration Technol. , 117 , 111, 2001
Liu MH, Chen Q, Lu K, Huang WQ, Lu ZH, Zhou CM, Yu SC, Gao CJ, Sep. Purif. Technol. , 173 , 135, 2017
Ozdemir O, Armagan B, Turan M, Celik MS, Dyes Pigment. , 62 , 49, 2004
de Luna MDG, Flores ED, Genuino DAD, Futalan CM, Wan MW, J. Taiwan Inst. Chem. Engineers , 44 , 646, 2013
Zubair M, Daud M, McKay G, Shehzad F, Al-Harthi MA, Appl. Clay Sci. , 143 , 279, 2017
Zaghouane-Boudiaf H, Boutahala M, Arab L, Chem. Eng. J. , 187 , 142, 2012
Bharali D, Deka RC, Colloids Surf. A: Physicochem. Eng. Asp. , 525 , 64, 2017
Lei CS, Zhu XF, Zhu BC, Jiang CJ, Le Y, Yu JG, J. Hazard. Mater. , 321 , 801, 2017
Cooper DR, D'Anjou B, Ghattamaneni N, Harack B, et al., ISRN Condensed Matter Phys., 1 (2012).
Daud M, Kamal MS, Shehzad F, Al-Harthi MA, Carbon , 104 , 241, 2016
Li YH, Du QJ, Liu TH, Peng XJ, Wang JJ, Sun JK, Wang YH, Wu SL, Wang ZH, Xia YZ, Xia LH, Chem. Eng. Res. Des. , 91 (2), 361, 2013
Alvarez MG, Tichit D, Medina F, Llorca J, Appl. Surf. Sci. , 396 , 821, 2017
Cao Y, Li GT, Li XB, Chem. Eng. J. , 292 , 207, 2016
Yuan XY, Wang YF, Wang J, Zhou C, Tang Q, Rao XB, Chem. Eng. J. , 221 , 204, 2013
Ruan XX, Chen YH, Chen H, Qian GR, Frost RL, Chem. Eng. J. , 297 , 295, 2016
Zhang YX, Hao XD, Kuang M, Zhao H, Wen ZQ, Appl. Surf. Sci. , 283 , 505, 2013
Lafi R, Charradi K, Djebbi MA, Amara ABH, Hafiane A, Adv. Powder Technol. , 27 (1), 232, 2016
Chen H, Zhao J, Wu JY, Dai GL, J. Hazard. Mater. , 192 (1), 246, 2011
Monash P, Pugazhenthi G, Environ. Prog. Sust. Energy , 33 , 154, 2014
Ma J, Yu F, Zhou L, Jin L, Yang M, Luan J, Tang Y, Fan H, Yuan Z, Chen J, ACS Appl. Mater. Interfaces , 4 , 5749, 2012
Redlich O, Peterson DL, J. Phys. Chem. , 63 , 1024, 1959
Zandipak R, Sobhanardakani S, Desalination Water Treatment , 57 , 11348, 2016
Tang S, Lee HK, Anal. Chem. , 85 , 7426, 2013
Roy S, Srivastava SK, Pionteck J, Mittal V, Macromol. Mater. Eng. , 300 , 346, 2015
Ferrer DI, in Supported Layered Double Hydroxides as CO2 Adsorbents for Sorption-enhanced H2 Production, 85 (2016).
Garcia-Gallastegui A, Iruretagoyena D, Gouvea V, Mokhtar M, Asiri AM, Basahel SN, Al-Thabaiti SA, Alyoubi AO, Chadwick D, Shaffer MSP, Chem. Mater. , 24 , 4531, 2012
Gao L, Li Q, Hu X, Wang X, Song H, Yan L, Xiao H, Appl. Clay Sci. , 126 , 299, 2016
Mallakpour S, Dinari M, J. Therm. Anal. Calorim. , 119 , 1905, 2015
Yang SX, Wang LY, Zhang XD, Yang WJ, Song GL, Chem. Eng. J. , 275 , 315, 2015
Chebli D, Bouguettoucha A, Reffas A, Tiar C, Boutahala M, Gulyas H, Amrane A, Desalination Water Treatment , 57 , 22061, 2016
El Hassani K, Beakou BH, Kalnina D, Oukani E, Anouar A, Appl. Clay Sci. , 140 , 124, 2017
Liu JY, Li XL, Luo JH, Duan C, Hu H, Qian GR, Chem. Eng. J. , 242 , 187, 2014
Sumari SM, Hamzah Z, Kantasamy N, Malaysian J. Anal. Sci. , 20 , 777, 2016
Goh KH, Lim TT, Dong Z, Water Res. , 42 , 1343, 2008
Deng L, Shi Z, Peng X, Zhou S, J. Alloy. Compd. , 688 , 101, 2016
Ho YS, McKay G, Process Biochem. , 34 (5), 451, 1999
Lu Y, Jiang B, Fang L, Ling F, Gao J, Wu F, Zhang X, Chemosphere , 152 , 415, 2016
Shan R, Yan L, Yang Y, Yang K, Yu S, Yu H, Zhu B, Du B, J. Ind. Eng. Chem. , 21 , 561, 2015
Wu FC, Tseng RL, Juang RS, Chem. Eng. J. , 153 (1-3), 1, 2009
Xin XD, Si W, Yao ZX, Feng R, Du B, Yan LG, Wei Q, J. Colloid Interface Sci. , 359 (2), 499, 2011
Zubair M, Jarrah N, Manzar MS, Al-Harthi M, Daud M, Mu’azu ND, Haladu SA, J. Mol. Liq. , 230 , 344, 2017
Shan RR, Yan LG, Yang K, Yu SJ, Hao YF, Yu HQ, Du B, Chem. Eng. J. , 252 , 38, 2014
Khalid A, Zubair M, Ihsanullah, Arabian J. Sci Eng. , 43 , 2167, 2018
Yao W, Yu SJ, Wang J, Zou YD, Lu SS, Ai YJ, Alharbi NS, Alsaedi A, Hayat T, Wang XK, Chem. Eng. J. , 307 , 476, 2017
Wang J, Kang DJ, Yu XL, Ge MF, Chen YT, Chem. Eng. J. , 264 , 506, 2015
Zhou QQ, Chen FF, Wu W, Bu R, Li W, Yang F, Chem. Eng. J. , 285 , 198, 2016
Dizge N, Aydiner C, Demirbas E, Kobya M, Kara S, J. Hazard. Mater. , 150 , 737, 2008
Jin Z, Wang X, Sun Y, Ai Y, Wang X, Environ. Sci. Technol. , 49 , 9168, 2015
Xiang W, Zhang GK, Zhang YL, Tang DD, Wang JT, Chem. Eng. J. , 250 , 423, 2014
Wang SL, Hseu RJ, Chang RR, Chiang PN, Chen JH, Tzou YM, Colloids Surf. A: Physicochem. Eng. Asp. , 277 , 8, 2006
Ganesan P, Kamaraj R, Vasudevan S, J. Taiwan Inst. Chem. Engineers , 44 , 808, 2013
Samuei S, Rezvani Z, Amani-Ghadim AR, Environ. Prog. Sust. Energy , 36 , 372, 2017
Chen D, Li Y, Zhang J, Li WH, Zhou JZ, Shao L, Qian GR, J. Hazard. Mater. , 243 , 152, 2012
Ai LH, Zhang CY, Meng LY, J. Chem. Eng. Data , 56 (11), 4217, 2011
Hu QH, Xu ZP, Qiao SZ, Haghseresht F, Wilson M, Lu GQ, J. Colloid Interface Sci. , 308 (1), 191, 2007
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