Korean Journal of Chemical Engineering, Vol.39, No.3, 646-654, 2022
17α-Ethinylestradiol elimination using synthesized and dense nanocomposite materials: Mechanism and real matrix treatment
Endocrine disrupting chemicals (EDCs) are emerging water contaminants and efficient elimination is a
greater challenge for environmental engineers. The present communication is intended to synthesize the novel dense nanocomposite materials precursors to the bentonite and 3-mercaptopropyletrimethoxy silane/or 3-aminopropyletriethoxy silane. The materials are highly dense, hence the surface area is significantly reduced compared to the pristine bentonite. Further, the materials are intended to be utilized in the elimination of one of the important EDC 17α-
ethinylestradiol (EE2). The sorption mechanism is greatly demonstrated based on various parametric studies. It is shown that grafted silane with bentonite network provides enhanced hydrophobicity with organophilic nature and greatly favors the uptake of EE2 at a wide range of pH (5.0-10.0). Relatively rapid uptake of EE2 by the nanocomposite solids followed by a pseudo-second-order kinetic model indicated that the materials are highly efficient for elimination of EE2. Increasing the concentration of EE2 (1.0 to 10.0mgL-1) favored the extent of removal of EE2 and followed the Langmuir adsorption isotherm. Further, the increase in background electrolytes by 1,000 times did not affect the
removal of EE2 by these nanocomposites, indicating the sorbing species are attracted with relatively stronger forces. Moreover, the simultaneous presence of several co-ions did not affect the percentage elimination of EE2; this, perhaps, shows an enhanced selectivity of materials towards the 17α-ethinylestradiol. A high loading capacity of EE2 is achieved under column reactor operation using these nanocomposites. Additionally, the materials are promising in the real matrix treatment.
[References]
Kosek K, Luczkiewicz A, Fudala-Ksi??ek S, Jankowska K, Szopi?ska M, Svahn O, Tr?nckner J, Kaiser A, Langas V, Bj?rklund E, Environ. Sci. Policy , 112 , 213, 2020
Lei M, Zhang L, Lei J, Zong L, Li J, Wu Z, Wang Z, BioMed. Res. Int. , 2015 , 1, 2015
Gavrilescu M, Demnerov? K, Aamand J, Agathos S, Fava F, New Biotechnol. , 32 , 147, 2015
Silva CP, Otero M, Esteves V, Environ. Pollut. , 165 , 38, 2012
Bennasroune A, Rojas L, Foucaud L, Goulaouic S, Laval-Gilly P,
Fickova M, Couleau N, Durandet C, Henry S, Falla J, Int. J. Immunopathol. Pharmacol. , 25 , 365, 2012
Tian S, Liu Y, Liu S, Zeng G, Jiang L, Tan X, Huang X, Yin Z, Liuab N, Liab J, RSC Adv. , 8 , 4273, 2018
Larcher S, Delb?s G, Robaire B, Yargeau V, Environ. Int. , 39 , 66, 2012
Han J, Qiu W, Cao Z, Hu J, Gao W, Water Res. , 47 , 2273, 2013
Essandoh HMK, Tizaoui C, Mohamed MHA, Sep. Sci. Technol. , 47 , 777, 2012
Oliveira HG, Ferreira LH, Bertazzoli R, Longo C, Water Res. , 72 , 305, 2015
Pauwels B, Wille K, Noppe H, De Brabander H, Van de Wiele T, Verstraete W, Boon N, Biodegradation , 19 , 683, 2008
Cargou?t M, Perdiz D, Mouatassim-Souali A, Tamisier-Karolak S, Levi Y, Sci. Total Environ. , 324 , 55, 2004
Atkinson SK, Marlatt VL, Kimpe LE, Lean DRS, Trudeau VL, Blais JM, Sci. Total Environ. , 430 , 119, 2012
De Assis S, Warri A, Cruz MI, Laja O, Tian Y, Zhang B, Wang Y, Huang THM, Hilakivi-Clarke L, Nat. Commun. , 3 , 1, 2012
Vandenberg LN, Colborn T, Hayes TB, Heindel JJ, Jacobs DR,
Jr., Lee DH, Myers JP, Shioda T, Soto AM, vom Saal FS, Reprod. Toxicol. , 38 , 1, 2013
Komesli OT, Muz M, Ak MS, Bak��rdere S, Gokcay CF, Chem. Eng. J. , 277 , 202, 2015
Scala-Benuzzi ML, Takara EA, Alderete M, Soler-Illia GJAA, Schneider RJ, Raba J, Messina GA, Microchem. J. , 141 , 287, 2018
Wit MD, Keil D, van der Ven K, Vandamme S, Witters E, Coen WD, Gen. Comp. Endocrinol. , 167 , 190, 2010
Feng Y, Zhang Z, Gao P, Su H, Yu Y, Ren N, J. Hazard. Mater. , 175 , 970, 2010
Kidd KA, Blanchfield PJ, Mills KS, Palace VP, Evans RE, Lazorchak JM, Flick RW, Proc. Natl. Acad. Sci. , 104 , 8897, 2007
Gao P, Liang Z, Zhao Z, Wang W, Yang C, Hu B, Cui F, Chemosphere , 234 , 438, 2019
Chaves FP, Gomes G, Della-Flora A, Dallegrave A, Sirtori C, Saggioro EM, Bila DM, Sci. Total Environ. , 746 , 141041, 2020
Wang S, Li L, Yu S, Dong B, Gao N, Wang X, Chem. Eng. J. , 406 , 126722, 2020
Castellanos RM, Bassin JP, Bila DM, Dezotti M, Environ. Pollut. , 274 , 116551, 2021
Anastopoulos I, Mittal A, Usman M, Mittal J, Yu G, N??ez-Delgado A, Kornaros M, J. Mol. Liq. , 269 , 855, 2018
Anjum H, Johari K, Gnanasundaram N, Ganesapillai M, Arunagiri A, Regupathi I, Thanabalan M, J. Mol. Liq. , 277 , 1005, 2019
Burham N, Sayed M, Minerals , 6 , 129, 2016
Zafar S, Khan MI, Lashari MH, Khraisheh M, Almomani F, Mirza ML, Khalid N, Emergent Mater. , 3 , 857, 2020
Soeiro TN, De Freitas ED, Maia GS, Santos AB, Vieira MGA, Guirardello R, Chem. Eng. Trans. , 57 , 619, 2017
Kyzas GZ, Fu J, Lazaridis NK, Bikiaris DN, Matis KA, J. Mol. Liq. , 209 , 87, 2015
He J, Guo J, Zhou Q, Yang J, Fang F, Huang Y, Chemosphere , 216 , 59, 2019
Burgos AE, Ribeiro-Santos TA, Lago RM, Water Sci. Technol. J. Int. Assoc. Water Pollut. Res. , 74 , 663, 2016
Dinesh GK, Chakma S, J. Taiwan Inst. Chem. Eng. , 100 , 95, 2019
Chauhan R, Dinesh GK, Alawa B, Chakma S, Chemosphere , 277 , 130324, 2021
Dinesh GK, Chakma S, Ultrason. Sonochem , 50 , 311, 2019
Kumar VV, Avisar D, Prasanna VL, Betzalel Y, Mamane H, J. Hazard. Mater. , 398 , 122880, 2020
Vaddadi LP, Avisar D, Vadivel VK, Menashe O, Kurzbaum E, Cohen-Yaniv V, Mamane H, Materials , 13 , 83, 2019
Mita L, Forte M, Rossi A, Adamo C, Rossi S, Mita DG, Guida M, Portaccio M, Godievargova T, Yavour I, Ann. Environ. Sci. Toxicol. , 2 , 48, 2017
Han J, Qiu W, Meng S, Gao W, Water Res. , 46 , 5715, 2012
Kumar AK, Mohan SV, Desalination , 276 , 66, 2011
Rudder J, Wiele TV, Dhooge W, Comhaire F, Verstraete W, Water Res. , 38 , 184, 2004
D?az-Quiroz C, Gonz?lez L, ?lvarez MS, Hernandez-Chavez JF, Rodriguez A, Delve FJ, Ulloa-Mercado G, Sep. Purif. Technol. , 250 , 117068, 2020
Belhadri M, Sassi M, Bengueddach A, J. Water Chem. Technol. , 41 , 357, 2019
Turan NG, Ozgonenel O, Sci. World J. , 2013 , 342628, 2013
Sen TK, Gomez D, Desalination , 267 , 286, 2011
Guo J, Chen S, Liu L, Li B, Yang P, Zhang L, Feng Y, J. Colloid Interface Sci. , 382 , 61, 2012
Tiwari D, Lee SM, Chem. Eng. J. , 204-206 , 23, 2012
Lee SM, Lalhmunsiama, Thanhmingliana, Tiwari D, Chem. Eng. J. , 270 , 496, 2015
Lalhmunsiama, Lee SM, Tiwari D, Chem. Eng. J. , 225 , 128, 2013
Lalchhingpuii, Tiwari D, Lalhmunsiama, Lee SM, Chem. Eng. J. , 328 , 434, 2017
Marjanovi? V, Lazarevi? S, Jankovi?-?astvan I, Potkonjak B, Jana?kovi? D, Petrovi? R, Chem. Eng. J. , 166 , 198, 2011
Sahan T, Erol F, Y��lmaz S, Microchem. J. , 138 , 360, 2018
Y��lmaz S, Sahan T, Karabakan A, Korean J. Chem. Eng. , 34 , 2225, 2017
Liang X, Xu Y, Sun G, Wang L, Sun Y, Sun Y, Qin X, Chem. Eng. J. , 174 , 436, 2011
Carvalho W, Vignado C, Fontana J, J. Hazard. Mater. , 153 , 1240, 2008
Perrotti TC, Freitas NS, Alzamora M, S?nchez DR, Carvalho NM, J. Environ. Chem. Eng. , 7 , 103237, 2019
Asgari M, Abouelmagd A, Sundararaj U, Appl. Clay Sci. , 146 , 439, 2017
Piscitelli F, Posocco P, Toth T, Fermeglia M, Pricl S, Mensitieri G, Lavorgna M, J. Colloid Interface Sci. , 351 , 108, 2010
Qin Z, Yuan P, Yang S, Liu D, He H, Zhu J, Appl. Clay Sci. , 99 , 229, 2014
Paul B, Martens WN, Frost RL, Appl. Surf. Sci. , 257 , 5552, 2011
Walcarius A, Etienne M, Bessi?re J, Chem. Mater. , 14 , 2757, 2002
Xue A, Zhou S, Zhao Y, Lu X, Han P, J. Hazard. Mater. , 194 , 7, 2011
Cui H, Qian Y, Li Q, Wei Z, Zhai J, Appl. Clay Sci. , 72 , 84, 2013
Ko?ak A, Lobnik A, Bauman M, Int. J. Appl. Ceram. Technol. , 12 , 461, 2015
Abeywardena SBY, Perera S, de Silva KMN, Tissera NP, Int. Nano Lett. , 7 , 237, 2017
Bui TX, Kang SY, Lee SH, Choi H, J. Hazard. Mater. , 193 , 156, 2011
Al-Khateeb LA, Obaid AY, Asiri NA, Salam MA, J. Ind. Eng. Chem. , 20 , 916, 2014
Lalhmunsiama, Lalchhingpuii, Nautiyal BP, Tiwari D, Choi SI, Kong SH, Lee SM, J. Colloid Interface Sci. , 467 , 203, 2016
Zhang Y, Zhou JL, Water Res. , 39 , 3991, 2005
Lalhmunsiama, Lee SM, Lalchhingpuii, Tiwari D, J. Environ. Chem. Eng. , 4 , 1537, 2016
Hasan Z, Choi EJ, Jhung SH, Chem. Eng. J. , 219 , 537, 2013
Vidal CB, Oliveira JT, Raulino GSC, de Q. Melo D, Pessoa GP, dos Santos AB, do Nascimento RF, XX Congresso Brasileiro
de Engenharia Quima. , 1 , 2, 2014
Lee SM, Tiwari D, Prasad SK, RSC Adv. , 5 , 46834, 2015
Ifelebuegu AO, Ukpebor JE, Obidiegwu CC, Kwofi BC, Glob. J. Environ. Sci. Manag. , 1 , 205, 2015
Thanhmingliana T, Lee SM, Tiwari D, Prasad SK, RSC Adv. , 5 , 46834, 2015
Joseph L, Zaib Q, Khan IA, Berge ND, Park YG, Saleh NB, Yoon Y, Water Res. , 45 , 4056, 2011
Gao P, Yang C, Liang Z, Wang W, Zhao Z, Hu B, Cui F, Chemosphere , 214 , 361, 2019
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