Korean Journal of Chemical Engineering, Vol.38, No.10, 2091-2105, 2021
Utilization of geothermal waste as a silica adsorbent for biodiesel purification
The purification process of biodiesel requires an adsorbent to reduce glycerin content releasing high purity of biodiesel. The adsorbent must be affordable in source and process, readily available, and have high adsorption capacity. This paper discusses utilization of silica aerogel from geothermal waste as an adsorbent of biodiesel to reduce glycerin. The paper investigates the potential of a high silica content of geothermal waste as silica adsorbent by observation of the glycerin adsorption capacity and its kinetics study. At the beginning, geothermal silica preparation was subjected to the purification of geothermal silica waste using sulfuric acid, sol-gel process, and drying process at ambient pressure. This research was statistically carried out by varying the volume ratio of HCl to sodium silicate (3-5), drying time (1-2 hours), and percent weight of silica (3-5%-w) using Design-Expert® Version 8.0.6 (State-Ease, Inc). The silica product was characterized through BET, FTIR, XRF, and XRD analysis. Analysis of untreated and treated biodiesel used GPC, GCMS, and titration based on Indonesian National Standard (SNI) of No. 06-1564-1995. The optimum conditions for preparation for removing glycerin in biodiesel was reached at ratio volume of HCl to sodium silicate of 3 : 1, 2 hours of drying time, and 3%-w silica adsorbent. The optimum of surface area of the s ilica adsorbent and the glycerin adsorption capacity can be attained at 371m2/g glycerin and 10±0.1 mg/g, respectively. Further meaning, the glycerin concentration in biodiesel can be reduced from (4±0.10)% to (0.1±0.01)% by using the silica adsorbent performing biodiesel characterization according to SNI in terms of glycerin content. The second-order pseudo model can be used to describe the glycerin adsorption in biodiesel by determination of k at 0.0036 g/mg min at the optimum condition preparation.
[References]
Kumar M, Sharma MP, Renew. Sust. Energ. Rev. , 56 , 1129, 2016
Pan SY, Li CW, Huang YZ, Fan C, Tai YC, Chen YL, Bioresour. Technol. , 318 , 124045, 2020
Yu KL, Chen WH, Sheen HK, Chang JS, Lin CS, Ong HC, Show PL, Ling TC, Fuel , 279 , 118435, 2020
Yusuff AS, Owolabi JO, South African J. Chem. Eng. , 30 , 42, 2019
Jacob A, Ashok B, Alagumalai A, Chyuan OH, Le PTK, Energy Conv. Manag. , 228 , 113655, 2020
Janaun J, Ellis N, Renew. Sust. Energ. Rev. , 14 , 1312, 2010
Kansedo J, Lee KT, Bhatia S, Biomass Bioenerg. , 33 (2), 271, 2009
Gashaw A, Teshita A, Int. J. Renew. Sustain. Energy , 3 , 92, 2014
Yu MJ, Jo YB, Kim SG, Lim YK, Jeon JK, Park SH, Kim SS, Park YK, Korean J. Chem. Eng. , 28 (12), 2287, 2011
Lee JH, Kim SB, Yoo HY, Lee JH, Han SO, Park C, Kim SW, Korean J. Chem. Eng. , 30 (6), 1335, 2013
Avinash A, Sasikumar P, Pugazhendhi A, Renew. Sust. Energ. Rev. , 134 , 110250, 2020
Saravanakumar A, Avinash A, Saravanakumar R, Energy Sources Part A-Recovery Util. Environ. Eff. , 38 (17), 2524, 2016
Agarwal M, Chauhan G, Chaurasia SP, Singh K, J. Taiwan Inst. Chem. Eng. , 43 , 89, 2012
Tacias-Pascacio VG, Torrestiana-Sanchez B, Dal Magro L, Virgen-Ortiz JJ, Suarez-Ruiz FJ, Rodrigues RC, Fernandez-Lafuente R, Renew. Energy , 135 , 1, 2019
Avinash A, Murugesan A, Sci. Rep. , 7 , 1, 2017
Pitakpoolsil W, Hunsom M, J. Environ. Manage. , 133 , 284, 2014
Kumar LR, Yellapu SK, Tyagi RD, Biodiesel production: technologies and future prospects, American Society of Civil Engineers, Washington (2019).
Pisarello ML, Costa BOD, Veizaga NS, Querini CA, Ind. Eng. Chem. Res. , 49 (19), 8935, 2010
Faccini CS, Da Cunha ME, Moraes MSA, Krause LC, et al., J. Braz. Chem. Soc. , 22 , 558, 2011
Cruz MCP, Ravagnani SP, Brogna FMS, et al., Biotechnol. Appl. Biochem. , 40 , 243, 2004
Berrios M, Skelton RL, Chem. Eng. J. , 144 (3), 459, 2008
Manique MC, Faccini CS, Onorevoli B, Benvenutti EV, Caramao EB, Fuel , 92 (1), 56, 2012
Santos FD, da Conceicao LRV, Ceron A, de Castro HF, Appl. Clay Sci. , 149 , 41, 2017
Gomes MG, Santos DQ, de Morais LC, Pasquini D, Fuel , 155 , 1, 2015
Squissato AL, Fernandes DM, Sousa RMF, Cunha RR, et al., Cellulose , 22 , 1263, 2015
Catarino M, Ferreira E, Dias APS, Gomes J, Chem. Eng. J. , 386 , 123930, 2020
Santos FD, Rafael L, Conceicao V, Giordani DS, De Castro HF, Int. J. Eng. Res. Sci. , 2 , 34, 2016
Yori JC, D'Ippolito SA, Pieck CL, Vera CR, Energy Fuels , 21 (1), 347, 2007
Predojevic ZJ, Fuel , 87 (17-18), 3522, 2008
Mazzieri VA, Vera CR, Yori JC, Energy Fuels , 22 (6), 4281, 2008
Ahmaruzzaman M, Gupta VK, Ind. Eng. Chem. Res. , 50 (24), 13589, 2011
Purnomo A, Dalanta F, Oktaviani AD, Silviana S, AIP Conf. Proc. , 2026 , 020077, 2018
Silviana S, Noorpasha A, Rahman MM, Civ. Eng. Archit. , 8 , 281, 2020
Silviana S, Darmawan A, Janitra AA, Ma’ruf A, Triesty I, Int. J. Emerg. Trends Eng. Res. , 8 , 4854, 2020
Musino D, Impact of surface modification on the structure and dynamics of silica-polymer nanocomposites, PhD diss., Universite Montpellier (2018).
Alswieleh AM, J. Chem. , 2020 , 1, 2020
Sarikhani K, Jeddi K, Thompson RB, Park CB, Chen P, Langmuir , 31 (20), 5571, 2015
Nguyen HKD, Hoang PT, Dinh NT, J. Braz. Chem. Soc. , 29 , 1714, 2018
Pal N, Mandal A, Chem. Eng. Sci. , 226 , 115887, 2020
Saengprachum N, Pengprecha S, Int. Conf. Life Sci. Eng. , 45 , 17, 2012
da Silva SR, de Albuquerque NJA, de Almeida RM, de Abreu FC, Materials , 10 , 1132, 2017
Raja SL, J. Chem. Nat. Resour. , 1 , 88, 2019
Kaya GG, Deveci H, J. Ind. Eng. Chem. , 89 , 13, 2020
Perdigoto MLN, Martins RC, Rocha N, Quina MJ, Gando-Ferreira L, Patricio R, Duraes L, J. Colloid Interface Sci. , 380 , 134, 2012
Moon JH, Ahn H, Hyun SH, Lee CH, Korean J. Chem. Eng. , 21 (2), 477, 2004
Ryu J, Kim SM, Choi JW, Ha JM, Ahn DJ, Suh DJ, Suh YW, Catal. Commun. , 29 , 40, 2012
Gurav JL, Jung IK, Park HH, Kang ES, Nadargi DY, J. Nanomater. , 2010 , 1, 2010
Motahari S, Nodeh M, Maghsoudi K, Desalin. Water Treat. , 57 , 16886, 2016
Li C, Zhu J, Zhou M, Zhang S, He X, Materials , 12 , 1782, 2019
Nah HY, Parale VG, Jung HNR, Lee KY, Lim CH, Ku YS, Park HH, J. Sol-Gel Sci. Technol. , 85 , 302, 2018
Rao AV, Kulkarni MM, Amalnerkar DP, Seth T, Appl. Surf. Sci. , 206 (1-4), 262, 2003
Zabeti M, Daud WMAW, Aroua MK, Fuel Process. Technol. , 91 (2), 243, 2010
Bangi UKH, Rao AV, Rao AP, Sci. Technol. Adv. Mater. , 9 , 035006, 2008
Li J, Wan C, Lu Y, Sun Q, Front. Agric. Sci. Eng. , 1 , 46, 2014
Pambudi NA, Itoi R, Yamashiro R, Alam BYCS, Tusara L, Jalilinasrabady S, Khasani J, Geothermics , 54 , 109, 2015
Silviana S, et al., Proceeding of Seminar Teknologi Hijau 2, 1, 341 (2017).
Silviana S, Sanyoto GJ, Darmawan A, Sutanto H, Rasayan J. Chem. , 13 , 1692, 2020
Silviana S, Rambe INH, Sudrajat H, Zidan MA, AIP Conf. Proc. , 2202 , 020069, 2019
Silviana S, Darmawan A, Subagio A, Dalanta F, ASEAN J. Chem. Eng. , 19 , 91, 2019
Silviana S, Darmawan A, Dalanta F, Subagio A, Hermawan F, Santoso HM, Materials , 14 , 1, 2021
Affandi S, Setyawan H, Winardi S, Purwanto A, Balgis R, Adv. Powder Technol. , 20 (5), 468, 2009
Lee SE, Ahn YS, Lee JS, Cho CH, Hong CK, Kwon OH, J. Ceram. Process. Res. , 18 , 777, 2017
Furqon F, Nugroho AK, Anshorulloh MK, Rona Tek. Pertan. , 12 , 22, 2019
Alves MJ, Cavalcanti IV, de Resende MM, Cardoso VL, Reis MH, Ind. Crop. Prod. , 89 , 119, 2016
Van Gerpen J, et al., Biodiesel analytical methods: August 2002-January 2004, National Renewable Energy Lab., United States (2004).
De Castro Vasques E, Tavares CRG, Yamamoto CI, Mafra MR, Igarashi-Mafra L, Environ. Technol. , 34 , 2361, 2013
Azmi MA, Ismail NAA, Rizamarhaiza M, Hasif AAKWM, Taib H, AIP Conf. Proc. , 1756 , 020005, 2016
Music S, Filipovic-Vincekovic N, Sekovanic L, Brazilian J. Chem. Eng. , 28 , 89, 2011
Anderson AM, Carroll MK, in Aerogels handbook, Adv. Sol-Gel Deriv. Materials Technol., New York (2011).
Tamon H, Kitamura T, Okazaki M, J. Colloid Interface Sci. , 197 (2), 353, 1998
Lazrag M, Lemaitre C, Castel C, Hannachi A, Barth D, J. Supercrit. Fluids , 140 , 394, 2018
Bajorath J, Chemoinformatics: Concepts, methods, and tools for drug discovery, Humana Press, New Jersey (2004).
Apostolopoulou-Kalkavoura V, Munier P, Bergstrom L, Adv. Mater. , 2001839 , 1, 2020
Ashraf MA, Peng W, Zare Y, Rhee KY, Nanoscale Res. Lett. , 13 , 1, 2018
Soytas SH, Oguz O, Menceloglu YZ, in Polymer composites with functionalized nanoparticles, Elsevier (2018).
Karamikamkar S, Naguib HE, Park CB, Adv. Colloid Interface Sci. , 276 , 102101, 2020
Jeon C, Kwang HP, Water Res. , 39 , 3938, 2005
Manuale DL, Greco E, Clementz A, Torres GC, Vera CR, Yori JC, Chem. Eng. J. , 256 , 372, 2014
Martin LS, Ceron A, Oliveira PC, Zanin GM, de Castro HF, J. Ind. Eng. Chem. , 62 , 462, 2018
Danish M, Mumtaz MW, Fakhar M, Rashid U, Chiang Mai J. Sci. , 44 , 1570, 2017
Fuller MP, Ritter GL, Draper CS, Appl. Spectrosc. , 42 , 217, 1988
Kongjao S, Damronglerd S, Hunsom M, Korean J. Chem. Eng. , 27 (3), 944, 2010
Stuart BH, Infrared spectroscopy: Fundamentals and applications, John Wiley & Sons, Ltd, Chichester (2005).
Raheem I, Mohiddin MNB, Tan YH, Kansedo J, Mubarak NM, Abdullah MO, Ibrahim ML, J. Ind. Eng. Chem. , 91 , 54, 2020
Chairgulprasert V, Madlah P, Sci. Technol. Asia , 23 , 1, 2018
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