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전압법에 의한 이성분(Acetone-Water)계의 등온기액 평형

Isothermal Vapor-Liquid Equilibrium for the Binary System Acetone-Water by the Total Pressure Method

HWAHAK KONGHAK, June 1974, 12(3), 179-188(10), NONE
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Abstract

전압법에 의하여 15℃, 25℃ 35℃, 45℃에서 acetone-water계의 등온기액평형 데이터를 얻었다.
평형증기조성을 계산하기 위하여 Barker's approximation method를 사용했으며 또한 Wilson parameter도 구했다.
등온기액평형 데이터를 이용하여 일정압력하의 기액평형 데이터를 추산하는 방법을 제시했으며 그 방법의 타당성을 확인했다.
Isothermal vapour-liquid equilibrium data was obtained by the total pressure method for the binary system acetone-water at 15℃, 25℃, 35℃, and 45℃, respectively.
Barker's approximation method was employed for the calculations of the vapour composition and Wilson parameters.
A new method of deriving vapour-liquid equilibrium data at constant pressure from isothermal vapour-liquid equilibria was presented and the calculated values using this method were found to be in good agreement with the literature values.

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