ISSN: 0304-128X ISSN: 2233-9558
Copyright © 2024 KICHE. All rights reserved

Articles & Issues

Conflict of Interest
In relation to this article, we declare that there is no conflict of interest.
articles This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.

All issues

질소가스의 저온흡착곡선에 의한 촉매의 Pore Size Distribution 결정

Determination of the Pore Size Distribution in Porous Catalysts from Nitrogen Isotherm

HWAHAK KONGHAK, August 1978, 16(4), 239-246(8), NONE
downloadDownload PDF

Abstract

촉매의 Pore Size Distribution을 얻는데 등온흡착 곡선이 사용될 수 있는데, 이와 관련하여 원통형 Pore내에서의 모세관 응축현상을 검토하고, 흡착상태와 액체상태의 열역학적 포텐샬이 서로 같지 않음을 고려해야 하고, 따라서 종래의 Kelvin식은 수정되어야 한다는 것을 설명한다. 또한 Pore Size Distribution을 계산하는 방법을 소개하고, 마지막에는 음극 산화 방법으로 만든 알루미나가 잘 정의된 원통형 Pore를 가지므로 이 시료에서 얻은 등온흡착 곡선을 분석하면 원통형 Pore 모델을 검토할 수 있음을 보여준다.
Regarding the nitrogen isotherm for obtaining the pore size distribution in porous catalysts, the capillary condensation models for cylindrical pore structure are reviewed, and it is shown that the traditional Kelvin equation should be modified by taking into consideration of the difference in thermodynamic potentials between the adsorbed state and the bulk liquid. The procedures of calculating the pore size distribution are explained, and anodic aluminas with well-defined cylindrical pores are proven to procide an excellent opportunity for the confirmation of the cylindrical pore model.

Keywords

The Korean Institute of Chemical Engineers. F5, 119, Anam-ro, Seongbuk-gu, 233 Spring Street Seoul 02856, South Korea.
Phone No. +82-2-458-3078FAX No. +82-507-804-0669E-mail : kiche@kiche.or.kr

Copyright (C) KICHE.all rights reserved.

- Korean Chemical Engineering Research 상단으로