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잔사유의 경질화

Upgrading of Petroleum Residue

HWAHAK KONGHAK, June 1982, 20(3), 187-198(12), NONE
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Abstract

잔사유 및 중유오일을 함유한 모래의 질을 개선하는 문제는, 이들 원료가 함유하고 있는 높은 금속 함유량이 촉매분해 또는 수소처리 등의 공정에 사용되는 촉매를 피독시킨다.
금속이 많이 함유된 원료는 코킹, 탈 아스팔트 공정, 수소생성 용매사용, 산 추출법 및 극성용매에 의한 침전 등의 방법을 사용한다.
코킹에 대한 용매, 탈 아스팔트 공정 등의 선택은 원유의 형에 따라 함수관계를 가진다. 그러나 타르의 처리문제는 아직 불확실하다.
잔사유의 경질화에 있어 가장 경제적인 공정은, 앞으로 잔사 수소처리공정이 주된 역할을 한 것으로 기대된다.
The shortage of crude oil supply placed an increased emphasis on methods of upgrading petroleum residue, heavy oil and oil bearing sands. However, the high metal content of these stocks will result in poisoning of the catalysts used in processes such as catalytic cracking, hydrocracking and hydrotreating.
For treatment of high metal feedstocks, processes such as coking, deasphalting, use of a hydrogen-donor solvent, extraction with acid, and precipitation with a polar solvent are used.
Selection of the most economic process route for residuum conversion is not straightforward; however, if crude oil price continues growing upward more rapidly than solid fuels do and if high sulfur tar and coke prices remain comparable with those of other fuels, then processes fo elimination of high sulfur by-products will become more attractive. With this in view, it is apparent that residuum hyroprocessing will play a major role in residuum conversion in the future.

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