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아연전해스라임으로부터 이산화망간의 회수
Recovery of Manganese Dioxide from Zinc Refinery Slimes
HWAHAK KONGHAK, December 1986, 24(6), 513-519(7), NONE
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Abstract
아연전해조에서 채취한 망간스라임에는 MnO2가 59.94 % 함유되어 있었다. 이 망간스라임을 물로 씻기, 환원배소, 용해추출, 용출액중의 불순물 제거 및 전해석출의 과정을 거쳐서 전해이산화망간을 합성하였다. 또한 X-선 회절분석에 의해 본 실험에서 합성된 MnO2는 전지활성이 우수한 γ형임을 알았다.
Manganese slimes which were formed in the zinc refinery electrolytic cells contained 59.94 % of MnO2. The recovery process of MnO2 from the slimes consisted of five steps, i.e., washing the slimes with water, roasting, dissolution of manganese, removal of impurities, and electrolytic synthesis of MnO2. By X-ray diffraction method it was proved that the recovered MnO2 had γ-typed crystalline structure.