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기포탑내에서의 n-프로판올과 iso-프로판올 수용액의 기체체류량에 관한 연구
A Study on Gas Holdup for Aqueous Solutions of n-Propanol and iso-Propanol in a Bubble Column
HWAHAK KONGHAK, April 1987, 25(2), 201-207(7), NONE
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Abstract
n-프로판올과 iso-프로판올의 제조에서 얻어지는 수용액을 증류할 때 각각 72 %(wt)와 88 %(wt) 농도에서 공비혼합물을 형성한다. 따라서, 이것들을 공비증류에 의하여 효과적으로 분리하기 위해서는 이것들이 기-액 접촉을 할 때 생성되는 기체의 체류량(holdup)을 아는 것이 중요하며, 이를 위해 이들 수용액의 농도, 점도, 온도, 그리고 표면장력과 기체분산판의 형태 및 기체유속변화에 따른 기체체류량을 측정하였다.
실험결과로부터 기체체류량에 대한 수용액의 표면장력, 점도, 기체유속, 분산판의 형태 등과의 상관성을 다음과 같이 수식화하였다.
φ((δ/D)․ε)(μLuG/σL)×1010 = KReGn
실험결과로부터 기체체류량에 대한 수용액의 표면장력, 점도, 기체유속, 분산판의 형태 등과의 상관성을 다음과 같이 수식화하였다.
φ((δ/D)․ε)(μLuG/σL)×1010 = KReGn
When aqueous solutions obtained from the production of n-propanol and iso-propanol are distilled, azeotropes are formed at the concentrations of 72 wt% and 88 wt% respectively. So it is important to predict the gas holdup in an aqueous solution with gas-liquid contact for the effective separation by the azeotropic distillation. In this study, the gas holdup of the solution was measured at the different concentration and temperature to investigate the effect of variable physical properties such as viscosity and surface tension along with different patterns of distribution plate and different gas velocity.
From the experimental result, a correlation between the gas holdup and surface tension and viscosity of aqueous solution, gas velocity, and pattern of distribution plate was found as follows;
φ((δ/D)․ε)(μLuG/σL)×1010 = KReGn
From the experimental result, a correlation between the gas holdup and surface tension and viscosity of aqueous solution, gas velocity, and pattern of distribution plate was found as follows;
φ((δ/D)․ε)(μLuG/σL)×1010 = KReGn