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묽은 고분자 수용액의 충류막에서 CO2의 물리적 흡수

Physical Absorption of CO2 in Laminar Falling Films of Dilute Polymeric Solutions

HWAHAK KONGHAK, June 1988, 26(3), 280-287(8), NONE
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Abstract

젖은 벽탑을 사용하여 뉴톤액체(PEG 수용액)와 지수법에 일치하는 비뉴톤액체(CMC 수용액)에 CO2 기체를 흡수시켜 CO2의 확산계수를 고분자 분자량 변화에 따라 측정하였다. 확산계수와 용액의 점도와의 관계를 다음과 같은 실험식으로 나타내었다.
25 ℃의 PEG 수용액에 대해서
D = 1.78×10-5·μ-(15.66/Mp0.515)
20 ℃ CMC수용액에 대해서
D = 1.57×10-5·μapp(78.18/Mp0.530)
Diffusion coefficients of CO2 in aqueous Newtonian solution of PEG(polyethylene glycol) and power-law non-Newtonian solution of CMC (sodium carboxymethyl cellulose) with molecular weights varying from 600 to 8,400 and from 32,300 to 136,800, respectively, were obtained from absorption rate measurements in a wetted-wall column. The diffusivity-viscosity relation is found to be a strong function of the molecular weight of the applied polymers. The data suggest thd following correlations.
For PEG solution at 25 ℃
D = 1.78×10-5·μ-(15.66/Mp0.515)
For CMC solution at 20℃,
D = 1.57×10-5·μapp(78.18/Mp0.530)
The diffusivity of CO2 in CMC solution was constant with respect to the change of the shear rate at the wall in the studied range of flow rate.

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