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저온에서 석탄으로부터 산소제거를 위한 SeO2의 촉매 효과 연구
Catalytic Effect of SeO2 on the Deoxygenation from Coal at Low Temperature
HWAHAK KONGHAK, August 1988, 26(4), 419-427(9), NONE
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Abstract
이산화 셀렌(SeO2)은 600 K(323 ℃) 이하에서 석탄에 포함된 산소를 선택적으로 제거시킴으로써 H/C의 원자비(atomic ratio)를 증가시키는 우수한 산소 제거능력이 있음을 실험적으로 증명하였다. 또한 반응온도가 낮아질수록 발생기체의 조성은 대부분 CO2로 구성되어 있으며 압력이 증가할수록 산소제거 능력은 증진되었다. 열분해를 통하여 발생한 함산소 기체인 CO와 CO2는 석탄에 포함된 관능기 중에서 주로 카르복실(-COOH) 혹은 하이드록실(-OH)기에 기인하고 있으며 카르보닐(=C=O)과 에테르(-O-)기는 촉매존재에 대하여 비교적 안정하였다.
Selenium Dioxide (SeO2) was experimentally observed to be an excellent selective catalyst which helps to remove oxygen from coal matrix and increase atomic H/C ratio at below 600 K(323 ℃). The evolved gas consisted mainly of carbon dioxide at a lower temperature range and the level of deoxygenation was highly enhanced at a higher pressure. The evolved oxygen-containing gases like CO and CO2 from thermal decomposition of coal in the presence of SeO2 were resulted from carboxylic and hydroxyl functional groups, whereas carbonyl and etheric functional groups were relatively inert to the cartlyst.