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제올라이트 담체상의 산화구리에 의한 황산화물과 질소산화물의 제거

Removal of SOX and NOX by Cupric Oxide Supported on Zeolite

HWAHAK KONGHAK, August 1989, 27(4), 588-594(7), NONE
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Abstract

고정발생원으로부터 나오는 황산화물과 질소산화물을 제올라이트 담체상의 산화구리를 이용하여 제거하는 실험을 하였다. 실험결과 CuO/Zeolite는 배기중 SOx 및 NOx의 제거에 적합한 만응물이며 반복재생 후에도 효율이 떨어지지 않는 것을 알 수 있었고 최적 반응온도는 400-450℃이었다. SO2 제거효율은 온도가 높을수록 증가하였으나 550℃ 이상에서는 생성된 CuSO4의 열분해로 인하여 감소하였고, SO2와 함께 NO를 제거시킬 경우에도 SO2의 반응 및 재생에는 영향이 없었으며, NO의 제거율은 거의 100%이었다. CuO/Zeolite와 SO2의 반응은 grain model을 사용하여 SO2농도에 대하여 1차인 화학반응율속으로 설명할 수 있었으며 반응속도상수는 다음과 같다.
k (cm/s) = 7.92exp[-12,450(cal/mol) /RT]
Removal of SOX and NOX from flue gas was experimented by using cupric oxide supported on zeolite. Experimental results showed that CuO/Zeolite is a good reactant for the removal of SO2 and NO from flue gas and the optimum reaction temperature is 400℃ to 450℃. Removal efficiency of SO2 was not decreased even after repeated cycles of removal and regeneration and it was increased with temperature but decreased at above 550℃ because of the thermal decomposition of CuSO4. In case of simultaneous removal of SO2 and NO, the efficiency of the removal and the regeneration of SO2 was not changed by the NO reaction and in particular the removal efficiency of NO was approx-imately 100 percent. The reaction of CuO/Aeolite with SO2 could be well explained by the grain model using 1st order chemical reaction control and the reaction rate constant was obtained as
k(cm/s)=7.92exp[-12,540(cal/mol)/RT].

Keywords

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