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액-액 계면에서의 물질전달-평판 교반조에 의한 액-액간 물질전달-
Mass Transfer Across Liquid-Liquid Interface-Mass Transfer in an Agitated Vessel with Liquid-Liquid Flat Interface-
HWAHAK KONGHAK, October 1990, 28(5), 594-601(8), NONE
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Abstract
불균일상의 액-액 계면을 통하여 전달되는 용질의 물질전단계수를 개량된 Lewis cell을 사용하여 측정하였다. 수용액상의 측정치 Sherwood수, Sh1를 수용액상의 Reynolds수, Re1, Schmidt수, Sc1, Capil-lary수, Ca1, 유기상의 Reynolds수, Re2 및 점도 보정치, Φ등과 같은 실험변수들을 사용하여 관련지었으며, 평균편차 15.3% 이내에서 다음과 같은 상관관계식을 얻을 수 있었다._x000D_
Sh1=0.0194Sh11/3 Ca16/13[Φ4Re13+Re28/3]1/4
The mass transfer coefficients of a solute through a flat interface of partially miscible binary systems were obtained in an agitated vessel of a modified Lewis cell type. The observed Sherwood number for an aqueous phase, Sh1 were correlated in terms of the aqueous Reynolds number, Re1, Schmidt number, Sc1, Capillary number, Ca1, a function of viscosity ratio, Ø and the organic phase Reynolds number, Re2. The correlation among these variables represented with an aberage deviation of 15.3% as the following equation._x000D_
Sh1=0.0194Sc11/3Ca16/13[Ø4Re13+Re28/3]1/4
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Wilke CR, Chang P, AIChE J., 1, 264 (1955)
Park SW, Han SB, Kim SS, Park TY, HWAHAK KONGHAK, 26(3), 280 (1988)
Marylin K, Mcclure DW, J. Chem. Edu., 47, 541 (1970)
Hikita H, Asai S, Ishikawa H, Saito Y, Chem. Eng. Sci., 30, 607 (1975)
Chun BS, Master Thesis, Pusan National University (1990)
Churchill SW, Usagi R, AIChE J., 18, 1211 (1972)
Beek WJ, Bakker CAP, Appl. Sci. Res., A10, 241 (1961)
Beveridge GS, Schechter RS, "Optiminization: Theory and Practice," McGraw-Hill, Inc., New York, p. 290 (1970)
Davies JT, "Turbulence Phenomena," Academic Press, New York, p. 141 (1972)
Davies JT, "Turbulence Phenomena," Academic Press, New York, p. 51 (1972)