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MRSM-1 모델을 이용한 Group-Group과 상호작용 파라미터 추산에 의한 3성분계 표현
The Representation of Ternary Systems by the Estimation of Group-Group and Interaction Parameters for MRSM-1 Model
HWAHAK KONGHAK, June 1991, 29(3), 284-299(16), NONE
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Abstract
새로운 추산방법의 하나로서, 2성분계 및 3성분계의 기상과 액상의 평형온도와 조성사이의 관계를 표현하는 MRSM-1 모델을 제시하였다. MRSM-1 모델을 이용하여 computer graphic에 의해 3성분계의 기액평형 등온선을 도시하였고, 도시된 등온선으로부터 공비점의 존재여부, 형태, 온도 그리고 조성의 주산이 가능해진다.
As one of the new estimation method, the MRSM-1 model which represents the relationship between equilibrium temperatures and compositions of vaper and liquid phase of the binary and ternary systems is proposed. By means of the MRSM-1 model, the temperatures of various compositions of five ternary systems are predicted. Representations of the isothermal lines and estimation of azeotropes are at-tempted using computer graphics. The MRSM-1 model provides a new method of predicting and depicting the isothermal lines, and existence and characteristics of the azeotropes of ternary systems.
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Lee LL, Startling KE, Fluid Phase Equilib., 21, 77 (1985)
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Lu BCY, Li JCH, Ting TW, Ind. Eng. Chem., 51, 219 (1959)
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Park JC, Theses Collection, Kyung Hee Univ., 15, 239 (1986)
Park JC, "Representation of Multiple Phase Response Surface by Means of Computer Graphics," Kyung Hee Univ., Publication, Seoul (1987)
Park JC, Ha DM, Theses Collection, Kyung Hee Univ., 16, 495 (1987)
Park JC, Kim MG, HWAHAK KONGHAK, 26(2), 194 (1988)
Park JC, "Mandang, Park, John-Chul, Ph.D., Full Professor, 60th Birthday Anniversary Theses Collection," Munyangsa, Seoul (1988)
Prausnitz JM, Lichtenthaler RN, deAzevedo EG, "Molecular Thermodynamics of Fluid-Phase Equilibria," Prentice-Hall Englewood Cliff, N.Y. (1986)
Redlich O, Kister AJ, Ind. Eng. Chem., 40, 345 (1948)
Reid RC, Prausnitz JM, Poling BE, "The Properties of Gases and Liquids," 4th Ed., McGraw-Hill (1987)
Shin HS, Park JC, Theses Collection, Kyung Hee Univ., 17, 497 (1988)
Wilson GM, J. Am. Chem. Soc., 86, 127 (1964)
Wohl K, Trans. AIChE., 42, 215 (1946)
Box GEP, Biometrics, 10, 16 (1954)
Chao KC, Hougen OA, Chem. Eng. Sci., 7, 246 (1958)
Chueh PL, Prausnitz JM, AIChE J., 13(6), 1107 (1967)
Fredenslund A, Gmehling J, Rasmussen P, "Vapor-Liquid Equilibrium Using UNIFAC," Elsevier (1979)
Gmehling J, Onken U, Arlt W, "Vapor-Liquid Equilibrium Data Collection," DECHEMA (1981)
Ha DM, Park JC, Theses Collection, Kyung Hee Univ., 14, 451 (1985)
Hill WJ, Hunter WG, Technometrics, 8, 571 (1966)
Hilm AK, Ellis SRM, Barkers PE, Br. Chem. Eng., 15(10), 1321 (1970)
Horsley LE, "Azeotropic Data III," Am. Chem. Soc. (1973)
Kim MG, Park JC, Theses Collection, Kyung Hee Univ., 14, 483 (1985)
King MB, "Phase Equilibrium in Mixture," Pergamon Press, N.Y. (1969)
Lee LL, Startling KE, Fluid Phase Equilib., 21, 77 (1985)
Lee LL, Chung FTH, Landis LH, Fluid Phase Equilib., 31, 253 (1986)
Lu BCY, Li JCH, Ting TW, Ind. Eng. Chem., 51, 219 (1959)
Malesinski W, "Azeotropy and Other Theoretical Problems of Vapor-Liquid Equilibrium," Polish Scientific Publishers, Warszawa (1965)
Morawetz H, "Macromolecular in Solution," John Wiley and Sons, Inc., N.Y. (1975)
Nagata I, J. Chem. Eng. Data, 7, 461 (1962)
Nakanishi K, Okazak S, Ikali K, Higuchi T, Tanaka H, J. Chem. Phys., 76, 629 (1982)
Park JC, "Prediction of Activity Coefficient for Non-Ideal Liquid Mixture," The 183rd Meeting of European Federation of Chem Engineers at Helsinki Finland, June (1977)
Park JC, Theses Collection, Kyung Hee Univ., 1, 509 (1980)
Park JC, Theses Collection, Kyung Hee Univ., 11, 139 (1982)
Park JC, PACHEC Proceeding, 2, 340 (1983)
Park JC, "Computer Estimation of Phase Response Surface," 1st ed., Kyung Hee Univ., Publication (1983)
Park JC, "Estimation of Multicomponent Phase Surface by Means of Response Surface Methodology and Comparison of Fitting for 3 and 4 Component Systems," Kyung Hee Univ., Publication, Seoul (1985)
Park JC, Theses Collection, Kyung Hee Univ., 15, 239 (1986)
Park JC, "Representation of Multiple Phase Response Surface by Means of Computer Graphics," Kyung Hee Univ., Publication, Seoul (1987)
Park JC, Ha DM, Theses Collection, Kyung Hee Univ., 16, 495 (1987)
Park JC, Kim MG, HWAHAK KONGHAK, 26(2), 194 (1988)
Park JC, "Mandang, Park, John-Chul, Ph.D., Full Professor, 60th Birthday Anniversary Theses Collection," Munyangsa, Seoul (1988)
Prausnitz JM, Lichtenthaler RN, deAzevedo EG, "Molecular Thermodynamics of Fluid-Phase Equilibria," Prentice-Hall Englewood Cliff, N.Y. (1986)
Redlich O, Kister AJ, Ind. Eng. Chem., 40, 345 (1948)
Reid RC, Prausnitz JM, Poling BE, "The Properties of Gases and Liquids," 4th Ed., McGraw-Hill (1987)
Shin HS, Park JC, Theses Collection, Kyung Hee Univ., 17, 497 (1988)
Wilson GM, J. Am. Chem. Soc., 86, 127 (1964)
Wohl K, Trans. AIChE., 42, 215 (1946)