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(CH3)2SiCl2-(CH3)3SiCl, (CH3)2SiCl2-CH3SiCl3, CH3SiCl3-(CH3)3SiCl계의 등온 기액평형에 관한 연구(2)
Isothermal Vapor-Liquid Equilibria of (CH3)2SiCl2-(CH3)3SiCl, (CH3)2SiCl2-CH3SiCl3, CH3SiCl3-(CH3)3SiCl Systems(2)
HWAHAK KONGHAK, December 1993, 31(6), 868-872(5), NONE
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Abstract
50℃의 등온하에서 Me2SiCl2(1)-Me3SiCl(2), Me2SiCl2(1)-MeSiCl3(2), MeSiCl3(1)-Me3SiCl(2)계의 기액평형실험을 headspace 가스크로마토그래피에 의해 수행하였다. 얻어진 결과는 Wilson, Van Larr, Margules, NRTL식에 상호 연관시켰다. 이러한 2성분계 메틸염화실란에 대한 실험적인 기액평형데이터를 분리조작의 기초데이터로 제시한다.
Isothermal vapor-liquid equilibria have been measured for Me2SiCl2(1)-Me3SiCl(2), Me2SiCl2(1)-Me3SiCl(2) and MeSiCl(1)-Me3SiCl(2) at 50℃ using headspace gas chromatography. The obtained results were correlated to the Wilson, Van Larr, Margules, NRTL equations. These experimental vapor-liquid equilib-rium data for binary system of methylchlorosilanes are presented as the basic data of separation process.
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SRI Report: "Process Economic Program Report," No. 160, SRI International (1983)
Rugina T, Sacarescu L, Gaspar M, Revista de Chimie, 39, 869 (1988)
Rugina T, Sacarescu L, J. Chem. Eng. Data, 37, 143 (1992)
Park SJ, Choi BH, Rhee BS, HWAHAK KONGHAK, 25(5), 512 (1987)
Park SJ, Rhee BS, HWAHAK KONGHAK, 28(4), 386 (1990)
Kim C, Koh J, Lee J, HWAHAK KONGHAK, 31(2), 154 (1993)
Gmehling J, Onken U, Arlt W, "Vapor-Liquid Equilibrium Data Collection," (1977)
