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폴리피롤 동특성 연구에 대한 개량 순환 전압 측정법
An Enhanced Cyclic Voltammetry Method for the Dynamic Property Study of Polypyrrole
동아대학교 화학공학과, 부산 604-714 1SEIKO 첨단기술연구소, Matsudo-shi, Chiba 270-2222
Dept. of Chem. Eng., Dong-A University, saha, Pusan 604-714, Korea 1Advanced Technolgy Center, SEIKO instrument Inc., Matsudo-shi, Chiba 270-2222, Japan
smjang@mail.donga.ac.kr
HWAHAK KONGHAK, August 2000, 38(4), 443-450(8), NONE
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Abstract
본 연구에서는 수정진동자와 UV/Vis를 동시에 사용하는 새로운 실험법을 소개함과 동시에 그 응용의 예로서 폴리피를 박막의 전기화학적인 산화-환원 반응을 조사하였고, 그 결과 전극 표면에서 일어나는 전기화학적인 메카니즘을 이해하는데 용이함을 알 수 있었다. 본 실험법은 전극/용액 계면 현상을 연구하기 위하여 수정진동자의 분석 변수, 전기화학적인 분석 변수, 그리고 UV/Vis의 분석 변수를 제공하여 전기화학적 물질 전달에 기인한 산화-환원 반응에 의한 전기화학적, 전기화학적 발광, 점탄성 특성, 질량 변화 그리고 광학적 성질 등에 대한 상관 관계를 제시하였다.
In this paper, we introduce a new experiment system of quartz crystal analyzer combined with UV/Vis spectroscopy. As an example of application, the electrochemical redox-process of polypyrrole has been investigated and the system was found to be effective to understand electrochemical mechanism occurred on the electrode surface. The QCA-UV/Vis system can provide plentiful analytical information, for the study of electrode/solution interface phenomena because the system can provide electrochemical, gravimetric and optical variables. In this paper, we suggest analytical relations for investigating the electrochromic, viscolestic property, mass change and optical property of the film due to electrochemical redox-process induced mass transportation.
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Chang SM, Kim JM, Park JS, Son TI, Hiroshi M, J. Korean Ind. Eng. Chem., 9(1), 44 (1998)
Chang SM, Kim JM, Song SH, Chang YK, Muramatsu H, HWAHAK KONGHAK, 36(2), 189 (1998)
Muramatsu H, Tamiya E, Karube I, Anal. Chem., 60, 2142 (1988)
Muramatsu H, Tamiya E, Suzuki M, Karube I, Anal. Chim. Acta, 215, 91 (1988)
Muramatsu H, Ye X, Suda M, Sakuhara T, Ataka T, J. Electroanal. Chem. Int. Electrochem., 322, 311 (1992)
Chang SM, Kim JM, Muramatsu H, Ataka T, Cho WJ, Ha CS, Polymer, 37(16), 3757 (1996)
Kim JM, Chang SM, Muramatsu H, Polymer, 40(12), 3291 (1999)
Kim JM, Chang SM, Muramatsu H, Appl. Phys. Lett., 74(3), 466 (1999)
Benes E, J. Appl. Phys., 56(3), 608 (1984)
Beck R, Pittermann U, Weil KG, Ber. Bunsenges. Phys. Chem., 92, 1363 (1988)
Martin SJ, Granstaff VE, Frye GC, Anal. Chem., 63, 2272 (1991)
Johannsmann D, Mathauer K, Wegner G, Knoll W, Phys. Rev., B, Condens. Matter, 46(12), 7808 (1992)
Glidle A, Hillman AR, Brucknstein S, J. Electroanal. Chem., 318, 411 (1991)
Takada K, Tatsuma T, Oyama N, Nomura T, J. Electroanal. Chem., 370(1), 103 (1994)
Rodahl M, Hook F, Kasemo B, Anal. Chem., 68, 2219 (1996)
Pei Q, Qian R, J. Electroanal. Chem., 322, 153 (1992)
Ohtsuka T, Wakabayashi T, Einaga H, J. Electroanal. Chem., 377(1), 107 (1994)
Maria H, Davis Y, Janos HF, Chem. Mater., 4, 209 (1992)
Yamato H, Ohwa M, Wernet W, J. Electroanal. Chem., 397(1), 163 (1995)
Macro DAF, Stefania P, Paola P, Scrosati B, Electrochim. Acta, 35(7), 1145 (1990)
Iseki M, Ikematsu M, Sugiyama Y, Tago I, Mizukami A, J. Electroanal. Chem., 386(1), 253 (1995)
Gros P, Bergel A, J. Electroanal. Chem., 386(1), 65 (1995)
Rosa CDP, Macro DAF, Synth. Met., 48, 259 (1992)
Diaz AF, Castillo JI, Logan JA, Lee WY, J. Electroanal. Chem., 129, 115 (1981)
Street GB, "Handbook of Conducting Polymers," edited by T.A. Skotheim, Marcel Dekker, N.Y. and Basel, 1, 265 (1986)
Kaneto K, Yoshino K, Kino Zairyo, 4, 8 (1984)
Amemiya T, Ito K, Fujishima A, Ber. Bunsenges. Phys. Chem., 93, 682 (1989)
Chiu HT, Lin JS, Shiau JN, J. Appl. Electrochem., 22, 522 (1992)
Marchesiello M, Genies EM, Electrochim. Acta, 37, 1987 (1992)
Koopal CGJ, Feiters MC, Nolte RJM, Ruiter BD, Schasfoort RBM, Biosensors Bioelectron., 7, 461 (1992)
Bartlett PN, Ling-Chung SK, Sensors Actuators, 20, 287 (1989)
Fabjian C, Frithum G, Hartl H, Ber. Bunsenges. Phys. Chem., 94, 937 (1990)
Cosnier S, Derozier A, J. Mol. Catal., 71, 203 (1992)
Diaz AF, Kanazawa KK, "Extended Linear Chain Compounds," edited by J.S. Miller, Plenum Press, N.Y., 3, 265 (1981)
Schlenoff JB, Chien CW, J. Am. Chem. Soc., 109(21), 6269 (1987)
Backer CK, Qiu YJ, Reynolds JR, J. Phys. Chem., 95, 4446 (1991)
Naoi K, Lien MM, Smyrl WH, J. Electroanal. Chem., 272, 273 (1989)
Naoi K, Lien MM, Smyrl WH, J. Electrochem. Soc., 138, 440 (1991)
Reinolds JR, Sundaresan NS, Pomerantz M, Basak S, Baker CK, J. Electroanal. Chem., 250, 355 (1988)
Pei Q, Renyuan Q, J. Electroanal. Chem., 322, 153 (1992)
Shimazu K, Yanagida M, Uosaki K, J. Electroanal. Chem., 350, 321 (1993)
Buttry DA, Ward MD, Chem. Rev., 92, 1355 (1992)
Sauerbrey G, Z. Phys., 115, 206 (1959)
Muramatsu H, Egawa A, Ataka T, J. Electroanal. Chem., 388(1), 89 (1995)
Kanazawa KK, Biomolecular Mechanism & Design Workshop '99 (Japan), 0-1-7 (1999)
Sarangapani S, Tilak BV, Chen CP, J. Electrochem. Soc., 143(11), 3791 (1996)
Barsukov V, Chivikov S, Electrochim. Acta, 40(11), 1773 (1996)
Mermilliod N, Tanguy J, Petiot F, J. Electrochem. Soc., 133(6), 1073 (1986)
Chang SM, Kim JM, Park JS, Son TI, Hiroshi M, J. Korean Ind. Eng. Chem., 9(1), 44 (1998)
Chang SM, Kim JM, Song SH, Chang YK, Muramatsu H, HWAHAK KONGHAK, 36(2), 189 (1998)
